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Structural diversity in hybrid vanadium(IV) oxyfluorides based on a common building block
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dc.contributor.author | Aidoudi, Farida H. | |
dc.contributor.author | Black, Cameron | |
dc.contributor.author | Arachchige, Kasun S. Athukorala | |
dc.contributor.author | Slawin, Alexandra M. Z. | |
dc.contributor.author | Morris, Russell E. | |
dc.contributor.author | Lightfoot, Philip | |
dc.date.accessioned | 2014-10-03T23:01:33Z | |
dc.date.available | 2014-10-03T23:01:33Z | |
dc.date.issued | 2014 | |
dc.identifier | 88782122 | |
dc.identifier | ba5eb693-6a2f-4edd-a2c5-e8dd252cc24f | |
dc.identifier | 000327894400024 | |
dc.identifier | 84890041832 | |
dc.identifier | 000327894400024 | |
dc.identifier.citation | Aidoudi , F H , Black , C , Arachchige , K S A , Slawin , A M Z , Morris , R E & Lightfoot , P 2014 , ' Structural diversity in hybrid vanadium(IV) oxyfluorides based on a common building block ' , Dalton Transactions , vol. 43 , no. 2 , pp. 568-575 . https://doi.org/10.1039/c3dt52385c | en |
dc.identifier.issn | 1477-9226 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/56861515 | |
dc.identifier.other | ORCID: /0000-0001-7048-3982/work/59464424 | |
dc.identifier.other | ORCID: /0000-0001-7809-0315/work/61622082 | |
dc.identifier.uri | https://hdl.handle.net/10023/5530 | |
dc.description.abstract | There are only limited reports on vanadium(IV) oxyfluorides (VOFs) with extended crystal structures. Here we expand and enrich the list of existing VOFs with a series of 14 new materials "VOF-n (n = 1-14)" prepared using ionothermal and solvothermal synthesis methods. All of these materials arise from the condensation of a dimeric structural motif. These VOFs can be classified into three groups depending on their key structural features; layer structures: VOF-1 "[HN2C7H6][V2O2F5]", VOF-2 "[HN2C4H4][V2O2F5]", VOF-3 "[HN2C3H4][V2O2F5]" and VOF-4 "V-2(N2C4H4)O2F4", ladder like structures: VOF-5 "[NH4(HN2C3H4)][V2O2F6]", VOF-6 "[K(HN2C3H4)][V2O2F6]", VOF-7 "[HNH2CH2CH3][VOF3]", VOF-8 "[HN2C7H6][VOF3]", VOF-9 "[H2N2C4H6][V2O2F6]", VOF-10 "beta-RbVOF3", VOF-11 "alpha-KVOF3", VOF-12 "beta-KVOF3", VOF-13 "[H-2(NH2)(2)(CH2)(2)][V2O2F6]", and a chain structure: VOF-14 "[H2N2C6H12][V2O2F7]". The crystal structures of VOF-n are presented, and their synthetic and structural relationships are discussed. | |
dc.format.extent | 8 | |
dc.format.extent | 1577592 | |
dc.language.iso | eng | |
dc.relation.ispartof | Dalton Transactions | en |
dc.subject | Hydrothermal synthesis | en |
dc.subject | Chemistry | en |
dc.subject | Polymer | en |
dc.subject | Chains | en |
dc.subject | QD Chemistry | en |
dc.subject.lcc | QD | en |
dc.title | Structural diversity in hybrid vanadium(IV) oxyfluorides based on a common building block | en |
dc.type | Journal article | en |
dc.contributor.sponsor | EPSRC | en |
dc.contributor.sponsor | EPSRC | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | 10.1039/c3dt52385c | |
dc.description.status | Peer reviewed | en |
dc.date.embargoedUntil | 2014-10-04 | |
dc.identifier.grantnumber | EP/K005499/1 | en |
dc.identifier.grantnumber | EP/F021925/1 | en |
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