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Organophosphorus-Selenium Heteroatom Derivatives from Selenation of Primary/Secondary Amines and Haloalkanes/Dihaloalkanes
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dc.contributor.author | Hua, Guoxiong | |
dc.contributor.author | Arachchige, Kasun S. A. | |
dc.contributor.author | Slawin, Alexandra M. Z. | |
dc.contributor.author | Woollins, J. Derek | |
dc.date.accessioned | 2014-09-23T23:01:36Z | |
dc.date.available | 2014-09-23T23:01:36Z | |
dc.date.issued | 2013-11 | |
dc.identifier | 112009834 | |
dc.identifier | 05004c92-c096-4563-a60c-feaa877a1c84 | |
dc.identifier | 000329872100022 | |
dc.identifier | 84887260292 | |
dc.identifier.citation | Hua , G , Arachchige , K S A , Slawin , A M Z & Woollins , J D 2013 , ' Organophosphorus-Selenium Heteroatom Derivatives from Selenation of Primary/Secondary Amines and Haloalkanes/Dihaloalkanes ' , European Journal of Organic Chemistry , vol. 2013 , no. 32 , pp. 7402-7410 . https://doi.org/10.1002/ejoc.201300860 | en |
dc.identifier.issn | 1434-193X | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/56861991 | |
dc.identifier.other | ORCID: /0000-0002-1498-9652/work/31779201 | |
dc.identifier.uri | https://hdl.handle.net/10023/5492 | |
dc.description.abstract | Reaction of 2,4-bis(phenyl)-1,3-diselenadiphosphetane-2,4-diselenide (Woollins' reagent) with four equivalents of primary/secondary amines led to a series of ammonium phenylphosphonamido-diselenoates or phenylphosphonamido-diselenoic diamides 1a-n, the latter further reacted in situ with either two equivalents of haloalkanes or an equimolar amount of dihaloalkane, resulting in formation of the corresponding Se-alkylphenyl-Se-alkylphenyl-phosphonamidodiselenoates 2a-n and alkane bis(N-alkyl-P-phenylphosphonamido-diselenoate) derivatives 3a-n in good to excellent yields. All new compounds have been characterized spectroscopically including multinuclear NMR (H-1, C-13, P-31 and Se-77), IR and mass spectroscopy. Two representative X-ray structures are also described. | |
dc.format.extent | 9 | |
dc.format.extent | 464243 | |
dc.language.iso | eng | |
dc.relation.ispartof | European Journal of Organic Chemistry | en |
dc.subject | Woollins' reagent | en |
dc.subject | Selenium | en |
dc.subject | Phosphorus | en |
dc.subject | Amines | en |
dc.subject | Haloalkanes | en |
dc.subject | Crystal structures | en |
dc.subject | QD Chemistry | en |
dc.subject.lcc | QD | en |
dc.title | Organophosphorus-Selenium Heteroatom Derivatives from Selenation of Primary/Secondary Amines and Haloalkanes/Dihaloalkanes | en |
dc.type | Journal article | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | https://doi.org/10.1002/ejoc.201300860 | |
dc.description.status | Peer reviewed | en |
dc.date.embargoedUntil | 2014-09-24 |
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