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dc.contributor.authorHua, Guoxiong
dc.contributor.authorArachchige, Kasun S. A.
dc.contributor.authorSlawin, Alexandra M. Z.
dc.contributor.authorWoollins, J. Derek
dc.date.accessioned2014-09-23T23:01:36Z
dc.date.available2014-09-23T23:01:36Z
dc.date.issued2013-11
dc.identifier.citationHua , G , Arachchige , K S A , Slawin , A M Z & Woollins , J D 2013 , ' Organophosphorus-Selenium Heteroatom Derivatives from Selenation of Primary/Secondary Amines and Haloalkanes/Dihaloalkanes ' , European Journal of Organic Chemistry , vol. 2013 , no. 32 , pp. 7402-7410 . https://doi.org/10.1002/ejoc.201300860en
dc.identifier.issn1434-193X
dc.identifier.otherPURE: 112009834
dc.identifier.otherPURE UUID: 05004c92-c096-4563-a60c-feaa877a1c84
dc.identifier.otherWOS: 000329872100022
dc.identifier.otherScopus: 84887260292
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861991
dc.identifier.otherORCID: /0000-0002-1498-9652/work/31779201
dc.identifier.urihttp://hdl.handle.net/10023/5492
dc.description.abstractReaction of 2,4-bis(phenyl)-1,3-diselenadiphosphetane-2,4-diselenide (Woollins' reagent) with four equivalents of primary/secondary amines led to a series of ammonium phenylphosphonamido-diselenoates or phenylphosphonamido-diselenoic diamides 1a-n, the latter further reacted in situ with either two equivalents of haloalkanes or an equimolar amount of dihaloalkane, resulting in formation of the corresponding Se-alkylphenyl-Se-alkylphenyl-phosphonamidodiselenoates 2a-n and alkane bis(N-alkyl-P-phenylphosphonamido-diselenoate) derivatives 3a-n in good to excellent yields. All new compounds have been characterized spectroscopically including multinuclear NMR (H-1, C-13, P-31 and Se-77), IR and mass spectroscopy. Two representative X-ray structures are also described.
dc.format.extent9
dc.language.isoeng
dc.relation.ispartofEuropean Journal of Organic Chemistryen
dc.rightsCopyright 2013, Wiley. This is the accepted version of the following article: Guoxiong, H. et al (2013). ‘Organophosphorus-Selenium Heteroatom Derivatives from Selenation of Primary/Secondary Amines and Haloalkanes/Dihaloalkanes’, European Journal of Organic Chemistry, Vol 2013 (32) pp. 7402–7410, which has been published in final form at: DOI: 10.1002/ejoc.201300860en
dc.subjectWoollins' reagenten
dc.subjectSeleniumen
dc.subjectPhosphorusen
dc.subjectAminesen
dc.subjectHaloalkanesen
dc.subjectCrystal structuresen
dc.subjectQD Chemistryen
dc.subject.lccQDen
dc.titleOrganophosphorus-Selenium Heteroatom Derivatives from Selenation of Primary/Secondary Amines and Haloalkanes/Dihaloalkanesen
dc.typeJournal articleen
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1002/ejoc.201300860
dc.description.statusPeer revieweden
dc.date.embargoedUntil2014-09-24


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