[Pd(NHC)(PR3)] complexes : versatile tools for tandem dehydrogenation-hydrogenation processes
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Homogeneous Pd(0) complexes are powerful tools for numerous catalytic reactions. Recent work has demonstrated the unique properties displayed by [Pd(NHC)(PR3)] catalysts in the activation of ammonia borane (AB) and formic acid, with the subsequent formation of hydrogen. An understanding of the mechanism allowed for the design of a new dehydrogenation-hydrogenation tandem process using hydrogen storage materials'. The hydrogenations of alkenes and alkynes were successfully performed at low catalyst loadings of Pd(0) species and mild conditions. Such tandem process represents a safe and innovative alternative to classic hydrogenation protocols.
Songis , O & Cazin , C S J 2013 , ' [Pd(NHC)(PR3)] complexes : versatile tools for tandem dehydrogenation-hydrogenation processes ' Synlett , vol. 24 , no. 15 , pp. 1877-1881 . DOI: 10.1055/s-0033-1339669
© 2013. Georg Thieme Verlag Stuttgart · New York. This is an Accepted Manuscript of an article published in the Synlett on 17 September 2013, available online: https://www.thieme-connect.de/products/ejournals/abstract/10.1055/s-0033-1339669
DescriptionThis work is supported in part by funding from the EPSRC UK
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