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Catalytic constructive deoxygenation of lignin-derived phenols: new C-C bond formation processes from imidazole-sulfonates and ether cleavage reactions

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dc.contributor.authorLeckie, Stuart M.
dc.contributor.authorHarkness, Gavin J.
dc.contributor.authorClarke, Matthew L.
dc.date.accessioned2014-09-05T09:31:02Z
dc.date.available2014-09-05T09:31:02Z
dc.date.issued2014-10-09
dc.identifier.citationLeckie , S M , Harkness , G J & Clarke , M L 2014 , ' Catalytic constructive deoxygenation of lignin-derived phenols: new C-C bond formation processes from imidazole-sulfonates and ether cleavage reactions ' , Chemical Communications , vol. 50 , no. 78 , pp. 11511-11513 . https://doi.org/10.1039/C4CC04939Jen
dc.identifier.issn1359-7345
dc.identifier.otherPURE: 145942842
dc.identifier.otherPURE UUID: 1256ccd8-2aa2-4197-850f-6e27ab612c2b
dc.identifier.otherBibtex: urn:9e2cb98ddba644e3d234a607ab59426a
dc.identifier.otherScopus: 84929600979
dc.identifier.otherORCID: /0000-0002-2444-1244/work/59464603
dc.identifier.otherWOS: 000341774200018
dc.identifier.urihttps://hdl.handle.net/10023/5352
dc.descriptionFunding: UK Engineering and Physical Sciences Research Council (EPSRC)en
dc.description.abstractAs part of a programme aimed at exploiting lignin as a chemical feedstock for less oxygenated fine chemicals, several catalytic C-C bond forming reactions utilising guaiacol imidazole sulfonate are demonstrated. These include the cross-coupling of a Grignard, a non-toxic cyanide source, a benzoxazole, and nitromethane. A modified Meyers reaction is used to accomplish a second constructive deoxygenation on a benzoxazole functionalised anisole.
dc.format.extent3
dc.language.isoeng
dc.relation.ispartofChemical Communicationsen
dc.rights© 2014. The Royal Society of Chemistry. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.en
dc.subjectQD Chemistryen
dc.subject.lccQDen
dc.titleCatalytic constructive deoxygenation of lignin-derived phenols: new C-C bond formation processes from imidazole-sulfonates and ether cleavage reactionsen
dc.typeJournal articleen
dc.contributor.sponsorEPSRCen
dc.contributor.sponsorEPSRCen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1039/C4CC04939J
dc.description.statusPeer revieweden
dc.identifier.urlhttp://dx.doi.org/10.1039/C4CC04939Jen
dc.identifier.grantnumberEP/J018139/1en
dc.identifier.grantnumberEP/J018139/1en


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