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Catalytic constructive deoxygenation of lignin-derived phenols: new C-C bond formation processes from imidazole-sulfonates and ether cleavage reactions
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dc.contributor.author | Leckie, Stuart M. | |
dc.contributor.author | Harkness, Gavin J. | |
dc.contributor.author | Clarke, Matthew L. | |
dc.date.accessioned | 2014-09-05T09:31:02Z | |
dc.date.available | 2014-09-05T09:31:02Z | |
dc.date.issued | 2014-10-09 | |
dc.identifier | 145942842 | |
dc.identifier | 1256ccd8-2aa2-4197-850f-6e27ab612c2b | |
dc.identifier | 84929600979 | |
dc.identifier | 000341774200018 | |
dc.identifier.citation | Leckie , S M , Harkness , G J & Clarke , M L 2014 , ' Catalytic constructive deoxygenation of lignin-derived phenols: new C-C bond formation processes from imidazole-sulfonates and ether cleavage reactions ' , Chemical Communications , vol. 50 , no. 78 , pp. 11511-11513 . https://doi.org/10.1039/C4CC04939J | en |
dc.identifier.issn | 1359-7345 | |
dc.identifier.other | Bibtex: urn:9e2cb98ddba644e3d234a607ab59426a | |
dc.identifier.other | ORCID: /0000-0002-2444-1244/work/59464603 | |
dc.identifier.uri | https://hdl.handle.net/10023/5352 | |
dc.description | Funding: UK Engineering and Physical Sciences Research Council (EPSRC) | en |
dc.description.abstract | As part of a programme aimed at exploiting lignin as a chemical feedstock for less oxygenated fine chemicals, several catalytic C-C bond forming reactions utilising guaiacol imidazole sulfonate are demonstrated. These include the cross-coupling of a Grignard, a non-toxic cyanide source, a benzoxazole, and nitromethane. A modified Meyers reaction is used to accomplish a second constructive deoxygenation on a benzoxazole functionalised anisole. | |
dc.format.extent | 3 | |
dc.format.extent | 1445414 | |
dc.language.iso | eng | |
dc.relation.ispartof | Chemical Communications | en |
dc.subject | QD Chemistry | en |
dc.subject.lcc | QD | en |
dc.title | Catalytic constructive deoxygenation of lignin-derived phenols: new C-C bond formation processes from imidazole-sulfonates and ether cleavage reactions | en |
dc.type | Journal article | en |
dc.contributor.sponsor | EPSRC | en |
dc.contributor.sponsor | EPSRC | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | https://doi.org/10.1039/C4CC04939J | |
dc.description.status | Peer reviewed | en |
dc.identifier.url | http://dx.doi.org/10.1039/C4CC04939J | en |
dc.identifier.grantnumber | EP/J018139/1 | en |
dc.identifier.grantnumber | EP/J018139/1 | en |
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