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Adsorption of a dihydro-TTF derivative on Au(111) via a thiolate bonding complex to gold adatoms

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dc.contributor.authorJethwa, Siddharth Janak
dc.contributor.authorGrillo, Federico
dc.contributor.authorFruchtl, Herbert Anton
dc.contributor.authorSimpson, Grant James
dc.contributor.authorTreanor, Michael John
dc.contributor.authorSchaub, Renald
dc.contributor.authorFrancis, Stephen Malcolm
dc.contributor.authorRichardson, Neville V
dc.contributor.authorAitken, R Alan
dc.date.accessioned2014-09-05T09:01:01Z
dc.date.available2014-09-05T09:01:01Z
dc.date.issued2014-08-05
dc.identifier132221986
dc.identifier7c7d3719-923f-4558-a70a-9a0c5f49275d
dc.identifier84905566697
dc.identifier000340707600036
dc.identifier.citationJethwa , S J , Grillo , F , Fruchtl , H A , Simpson , G J , Treanor , M J , Schaub , R , Francis , S M , Richardson , N V & Aitken , R A 2014 , ' Adsorption of a dihydro-TTF derivative on Au(111) via a thiolate bonding complex to gold adatoms ' , Chemical Communications , vol. 50 , no. 70 , pp. 10140-10143 . https://doi.org/10.1039/c4cc04130een
dc.identifier.issn1359-7345
dc.identifier.otherORCID: /0000-0001-9961-1212/work/29708440
dc.identifier.otherORCID: /0000-0001-6959-5311/work/34857583
dc.identifier.otherORCID: /0000-0001-6647-4266/work/60887493
dc.identifier.urihttps://hdl.handle.net/10023/5351
dc.descriptionFunding: Scottish Governmenten
dc.description.abstractA dihydro-TTF derivative with four acetyl-protected thiol ligands was synthesised and adsorbed on Au(111) under UHV conditions. Scanning Tunnelling Microscopy (STM) and Infrared (IR) spectroscopy show that self-organised structures are formed following annealing to 333 K, with each pair of bidentate thiolate ligands bonding to a single gold adatom in a S–Auad–S complex. Due to the lack of a direct orbital overlap between the dihydro-TTF moieties and the surface, relatively little charge transfer between TAT-TTF and the gold surface occurs.
dc.format.extent4
dc.format.extent3781837
dc.language.isoeng
dc.relation.ispartofChemical Communicationsen
dc.subjectQD Chemistryen
dc.subject.lccQDen
dc.titleAdsorption of a dihydro-TTF derivative on Au(111) via a thiolate bonding complex to gold adatomsen
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doi10.1039/c4cc04130e
dc.description.statusPeer revieweden


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