Show simple item record

Files in this item


Item metadata

dc.contributor.authorJethwa, Siddharth Janak
dc.contributor.authorGrillo, Federico
dc.contributor.authorFruchtl, Herbert Anton
dc.contributor.authorSimpson, Grant James
dc.contributor.authorTreanor, Michael John
dc.contributor.authorSchaub, Renald
dc.contributor.authorFrancis, Stephen Malcolm
dc.contributor.authorRichardson, Neville V
dc.contributor.authorAitken, R Alan
dc.identifier.citationJethwa , S J , Grillo , F , Fruchtl , H A , Simpson , G J , Treanor , M J , Schaub , R , Francis , S M , Richardson , N V & Aitken , R A 2014 , ' Adsorption of a dihydro-TTF derivative on Au(111) via a thiolate bonding complex to gold adatoms ' , Chemical Communications , vol. 50 , no. 70 , pp. 10140-10143 .
dc.identifier.otherPURE: 132221986
dc.identifier.otherPURE UUID: 7c7d3719-923f-4558-a70a-9a0c5f49275d
dc.identifier.otherScopus: 84905566697
dc.identifier.otherORCID: /0000-0001-9961-1212/work/29708440
dc.identifier.otherORCID: /0000-0001-6959-5311/work/34857583
dc.identifier.otherWOS: 000340707600036
dc.identifier.otherORCID: /0000-0001-6647-4266/work/60887493
dc.descriptionFunding: Scottish Governmenten
dc.description.abstractA dihydro-TTF derivative with four acetyl-protected thiol ligands was synthesised and adsorbed on Au(111) under UHV conditions. Scanning Tunnelling Microscopy (STM) and Infrared (IR) spectroscopy show that self-organised structures are formed following annealing to 333 K, with each pair of bidentate thiolate ligands bonding to a single gold adatom in a S–Auad–S complex. Due to the lack of a direct orbital overlap between the dihydro-TTF moieties and the surface, relatively little charge transfer between TAT-TTF and the gold surface occurs.
dc.relation.ispartofChemical Communicationsen
dc.rights© 2014. The Royal Society of Chemistry. This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.en
dc.subjectQD Chemistryen
dc.titleAdsorption of a dihydro-TTF derivative on Au(111) via a thiolate bonding complex to gold adatomsen
dc.typeJournal articleen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.description.statusPeer revieweden

This item appears in the following Collection(s)

Show simple item record