A general synthetic route to [Cu(X)(NHC)] (NHC = N-heterocyclic carbene, X = Cl, Br, I) complexes
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A one-pot procedure for the synthesis of [Cu(X)(NHC)] (X = Cl, Br, I) is reported. The reaction is applicable to a wide range of saturated and unsaturated NHC ligands, is scalable and proceeds under mild conditions using technical grade solvents in air.
Santoro , O , Collado-Martinez , A , Slawin , A M Z , Nolan , S P & Cazin , C S J 2013 , ' A general synthetic route to [Cu(X)(NHC)] (NHC = N-heterocyclic carbene, X = Cl, Br, I) complexes ' Chemical Communications , vol 49 , pp. 10483-10485 . DOI: 10.1039/c3cc45488f
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