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Structure and spectroscopy of hydrogen adsorbed in a nickel metal-organic framework

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dc.contributor.authorBrown, Craig M.
dc.contributor.authorRamirez-Cuesta, Anibal Javier
dc.contributor.authorHer, Jae-Hyuk
dc.contributor.authorWheatley, Paul S.
dc.contributor.authorMorris, Russell E.
dc.date.accessioned2014-08-27T23:01:37Z
dc.date.available2014-08-27T23:01:37Z
dc.date.issued2013-12-12
dc.identifier103314640
dc.identifier39d7c5b1-8d66-453f-9f3e-471e7210921c
dc.identifier000327773900002
dc.identifier84890130594
dc.identifier.citationBrown , C M , Ramirez-Cuesta , A J , Her , J-H , Wheatley , P S & Morris , R E 2013 , ' Structure and spectroscopy of hydrogen adsorbed in a nickel metal-organic framework ' , Chemical Physics , vol. 427 , pp. 3-8 . https://doi.org/10.1016/j.chemphys.2013.08.010en
dc.identifier.issn0301-0104
dc.identifier.otherORCID: /0000-0001-7809-0315/work/61622062
dc.identifier.urihttps://hdl.handle.net/10023/5266
dc.description.abstractThe structure of Ni-2(dobdc) (dobdc(4) = 2,5-dioxido-1,4-benzenedicarboxylate) as a function of deuterium adsorption has been determined through the application of in situ neutron powder diffraction. Detailed information concerning the local adsorption potential for hydrogen at each site has also been probed using inelastic neutron scattering techniques. These results are compared to those previously published on isostructural analogs and the Ni2+ variant shows the shortest deuterium-metal distance in the M-2(dobdc) series (M = Mg, Zn, Co, Fe) that have been studied so far.
dc.format.extent6
dc.format.extent1346173
dc.language.isoeng
dc.relation.ispartofChemical Physicsen
dc.subjectNeutron scatteringen
dc.subjectHydrogen storageen
dc.subjectMetal-organic frameworken
dc.subjectPorous crystalen
dc.subjectNeutron powder diffractionen
dc.subjectHigh H-2 adsorptionen
dc.subjectCoordination polymeren
dc.titleStructure and spectroscopy of hydrogen adsorbed in a nickel metal-organic frameworken
dc.typeJournal articleen
dc.contributor.sponsorEPSRCen
dc.contributor.sponsorEPSRCen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doi10.1016/j.chemphys.2013.08.010
dc.description.statusPeer revieweden
dc.date.embargoedUntil2014-08-28
dc.identifier.grantnumberEP/K005499/1en
dc.identifier.grantnumberEP/K025112/1en


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