Tris(2,2'-bipyridine)iron(II) bis(1,1,3,3-tetracyano-2-ethoxypropenide) dihydrate : chiral hydrogen-bonded frameworks interpenetrate in three dimensions
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In the title compound, [Fe(C10H8N2)3](C9H5N4O)2·2H2O, the chiral cations lie across twofold rotation axes in the space group C2/c. The anions and the water molecules are linked by two independent O-H⋯N hydrogen bonds to form C22(8) chains, and these chains are linked by the cations via C-H⋯N and C-H⋯O hydrogen bonds to form two interpenetrating three-dimensional frameworks, each of which contains only one enantiomeric form of the chiral cation.
Setifi , Z , Setifi , F , Boughzala , H , Beghidja , A & Glidewell , C 2014 , ' Tris(2,2'-bipyridine)iron(II) bis(1,1,3,3-tetracyano-2-ethoxypropenide) dihydrate : chiral hydrogen-bonded frameworks interpenetrate in three dimensions ' , Acta Crystallographica Section C Structural Chemistry , vol. 70 , no. 5 , pp. 465-469 . https://doi.org/10.1107/S2053229614008092
Acta Crystallographica Section C Structural Chemistry
© 2014 International Union of Crystallography.
DescriptionThe authors acknowledge the Algerian Ministry of Higher Education and Scientific Research, the Algerian Directorate-General for Scientific Research and Technological Development, and Ferhat Abbas Setif 1 University for financial support.
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