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Coordination polymer chains built from CuII and adipate ions linked by hydrogen bonds to form a three-dimensional framework structure
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dc.contributor.author | Setifi, Z. | |
dc.contributor.author | Boutebdja, M. | |
dc.contributor.author | Setifi, F. | |
dc.contributor.author | Merazig, H. | |
dc.contributor.author | Glidewell, C. | |
dc.date.accessioned | 2014-08-27T13:31:01Z | |
dc.date.available | 2014-08-27T13:31:01Z | |
dc.date.issued | 2014-07-01 | |
dc.identifier | 143740376 | |
dc.identifier | c4419dcb-deb9-4351-8f88-8546b5aa598f | |
dc.identifier | 84905497998 | |
dc.identifier | 000339013000015 | |
dc.identifier.citation | Setifi , Z , Boutebdja , M , Setifi , F , Merazig , H & Glidewell , C 2014 , ' Coordination polymer chains built from Cu II and adipate ions linked by hydrogen bonds to form a three-dimensional framework structure ' , Acta Crystallographica Section C Structural Chemistry , vol. 70 , no. 7 , pp. 702-706 . https://doi.org/10.1107/S205322961401359X | en |
dc.identifier.issn | 2053-2296 | |
dc.identifier.uri | https://hdl.handle.net/10023/5254 | |
dc.description.abstract | In the title compound, catena-poly[bis[(2,2'-bipyridine-κ2N,N')(1,1,3,3-tetracyano-2-ethoxypropenido-κN)copper(II)]-μ4- hexanedioato-κ6O1,O1:O1 :O6,O6':O6], [Cu2(C9H5N4O)2(C6H8O4)(C10H8N2)2]n , the adipate (hexanedioate) dianion lies across a centre of inversion in the space group P. The CuII centre adopts a distorted form of axially elongated (4+2) coordination, and the CuII and adipate components form a one-dimensional coordination polymer from which the 2,2'-bipyridine and 1,1,3,3-tetracyano-2-ethoxypropenide components are pendent, and where each adipate dianion is bonded to four different CuII centres. The coordination polymer chains are linked into a three-dimensional framework structure by a combination of C-H⋯N and C-H⋯O hydrogen bonds, augmented by a π-π stacking interaction. | |
dc.format.extent | 5 | |
dc.format.extent | 654621 | |
dc.language.iso | eng | |
dc.relation.ispartof | Acta Crystallographica Section C Structural Chemistry | en |
dc.subject | Crystal structure | en |
dc.subject | One-dimensional coordination polymer | en |
dc.subject | Copper(II) complex | en |
dc.subject | Adipate | en |
dc.subject | pi-pi stacking interactions | en |
dc.subject | 2,2'-bipyridine | en |
dc.subject | Polynitrile anions | en |
dc.subject | 1,1,3,3-tetracyano-2-ethoxypropenide | en |
dc.subject | QD Chemistry | en |
dc.subject.lcc | QD | en |
dc.title | Coordination polymer chains built from CuII and adipate ions linked by hydrogen bonds to form a three-dimensional framework structure | en |
dc.type | Journal article | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.identifier.doi | 10.1107/S205322961401359X | |
dc.description.status | Peer reviewed | en |
dc.identifier.url | http://www.scopus.com/inward/record.url?eid=2-s2.0-84905497998&partnerID=8YFLogxK | en |
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