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dc.contributor.authorTrilleras, J.
dc.contributor.authorUtria, M.
dc.contributor.authorCobo, J.
dc.contributor.authorGlidewell, C.
dc.date.accessioned2014-08-27T10:01:07Z
dc.date.available2014-08-27T10:01:07Z
dc.date.issued2014-02-01
dc.identifier143707841
dc.identifierd0924c1a-7911-4dc2-8575-499596899905
dc.identifier84901483745
dc.identifier000332218000022
dc.identifier.citationTrilleras , J , Utria , M , Cobo , J & Glidewell , C 2014 , ' (E)-1-[(5-Chloro-3-methyl-1-phenyl-1H-pyrazol-4-yl)methylidene] -2-phenylhydrazine : sheets built from π-stacked hydrogen-bonded chains ' , Acta Crystallographica Section C: Crystal Structure Communications , vol. 70 , no. 2 , pp. 216-219 . https://doi.org/10.1107/S2053229614000680en
dc.identifier.issn0108-2701
dc.identifier.urihttps://hdl.handle.net/10023/5248
dc.descriptionThe authors thank `Centro de Instrumentación Científico-Técnica of Universidad de Jaén' and the staff for data collection. JT and MU thank UNIATLANTICO (Universidad del Atlántico, Colombia) for financial support. JC thanks the Consejería de Innovación, Ciencia y Empresa (Junta de Andalucía, Spain) and the Universidad de Jaén for financial support.en
dc.description.abstractThe reaction between 5-chloro-3-methyl-1-phenyl-1H-pyrazole-4-carbaldehyde and phenylhydrazine proceeds via condensation to provide the title compound, C17H15ClN4, (I), rather than via the alternative routes of simple nucleophilic substitution or cyclocondensation. With the exception of the phenyl group bonded directly to the pyrazole ring, the non-H atoms of (I) are nearly coplanar, with an r.m.s. deviation of 0.058Å. The molecules are linked into C(7) chains by a single N - H⋯N hydrogen bond, and the chains are linked by π-π stacking interactions to form sheets.
dc.format.extent4
dc.format.extent507407
dc.language.isoeng
dc.relation.ispartofActa Crystallographica Section C: Crystal Structure Communicationsen
dc.subjectCrystal structureen
dc.subjectpi-stacked hydrogen-bonded chainsen
dc.subjectCondensation reactionen
dc.subjectPhenyl­hydrazine derivativeen
dc.subjectQD Chemistryen
dc.subject.lccQDen
dc.title(E)-1-[(5-Chloro-3-methyl-1-phenyl-1H-pyrazol-4-yl)methylidene] -2-phenylhydrazine : sheets built from π-stacked hydrogen-bonded chainsen
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.identifier.doi10.1107/S2053229614000680
dc.description.statusPeer revieweden
dc.identifier.urlhttp://www.scopus.com/inward/record.url?eid=2-s2.0-84901483745&partnerID=8YFLogxKen
dc.identifier.urlhttp://scripts.iucr.org/cgi-bin/sendsup?cnor=sf3218&type=supplementarymaterialsen


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