1,1'-Diethyl-4,4'-bipyridine-1,1'-diium bis(1,1,3,3-tetracyano-2- ethoxypropenide) : multiple C-H⋯N hydrogen bonds form a complex sheet structure

Setifi, Z.; Lehchili, F.; Setifi, F.; Beghidja, A.; Ng, S.W.; Glidewell, C.

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dc.contributor.author	Setifi, Z.
dc.contributor.author	Lehchili, F.
dc.contributor.author	Setifi, F.
dc.contributor.author	Beghidja, A.
dc.contributor.author	Ng, S.W.
dc.contributor.author	Glidewell, C.
dc.date.accessioned	2014-08-27T10:01:04Z
dc.date.available	2014-08-27T10:01:04Z
dc.date.issued	2014-03-01
dc.identifier.citation	Setifi , Z , Lehchili , F , Setifi , F , Beghidja , A , Ng , S W & Glidewell , C 2014 , ' 1,1'-Diethyl-4,4'-bipyridine-1,1'-diium bis(1,1,3,3-tetracyano-2- ethoxypropenide) : multiple C-H⋯N hydrogen bonds form a complex sheet structure ' , Acta Crystallographica Section C: Crystal Structure Communications , vol. 70 , no. 3 , pp. 338-341 . https://doi.org/10.1107/S2053229614004379	en
dc.identifier.issn	0108-2701
dc.identifier.other	PURE: 143705613
dc.identifier.other	PURE UUID: 6f2fb0c0-fee3-43f2-8b8b-f11881c40c5b
dc.identifier.other	Scopus: 84904855069
dc.identifier.other	WOS: 000332221900020
dc.identifier.uri	https://hdl.handle.net/10023/5246
dc.description	The authors acknowledge the Algerian ATRST (Agence The´matique de Recherche en Sciences et Technologie; PNR project) and the Ministry of Higher Education of Malaysia (grant No. UM.C/HIR-MOHE/SC/03) for financial support.	en
dc.description.abstract	In the title salt, C14H18N22+·2C9H5N4O−, the 1,1′-diethyl-4,4′-bipyridine-1,1′-diium dication lies across a centre of inversion in the space group P21/c. In the 1,1,3,3-tetracyano-2-ethoxypropenide anion, the two independent –C(CN)2 units are rotated, in conrotatory fashion, out of the plane of the central propenide unit, making dihedral angles with the central unit of 16.0 (2) and 23.0 (2)°. The ionic components are linked by C—H⋯N hydrogen bonds to form a complex sheet structure, within which each cation acts as a sixfold donor of hydrogen bonds and each anion acts as a threefold acceptor of hydrogen bonds.
dc.format.extent	4
dc.language.iso	eng
dc.relation.ispartof	Acta Crystallographica Section C: Crystal Structure Communications	en
dc.rights	Copyright 2014 International Union of Crystallography	en
dc.subject	Crystal structure	en
dc.subject	Hydrogen-bonded sheets	en
dc.subject	Polynitrile anions	en
dc.subject	4,4′-bipyridine-1,1′-diium	en
dc.subject	1,1,3,3-tetracyano-2-ethoxypropenide	en
dc.subject	QD Chemistry	en
dc.subject.lcc	QD	en
dc.title	1,1'-Diethyl-4,4'-bipyridine-1,1'-diium bis(1,1,3,3-tetracyano-2- ethoxypropenide) : multiple C-H⋯N hydrogen bonds form a complex sheet structure	en
dc.type	Journal article	en
dc.description.version	Publisher PDF	en
dc.contributor.institution	University of St Andrews. School of Chemistry	en
dc.identifier.doi	https://doi.org/10.1107/S2053229614004379
dc.description.status	Peer reviewed	en
dc.identifier.url	http://www.scopus.com/inward/record.url?eid=2-s2.0-84904855069&partnerID=8YFLogxK	en

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