Nickel-catalysed carboxylation of organoboronates
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A nickel/N-heterocyclic carbene (NHC) catalysed carboxylation of aryl-, heteroaryl- and alkenylboronates, affording the corresponding carboxylic acids, has been developed. This transformation proceeds under one atmosphere of CO2 with a broad range of substrates and exhibits good functional group compatibility.
Makida , Y , Marelli , E , Slawin , A M Z & Nolan , S P 2014 , ' Nickel-catalysed carboxylation of organoboronates ' Chemical Communications , vol. 50 , no. 59 , pp. 8010-8013 . DOI: 10.1039/C4CC03650F
© Royal Society of Chemistry 2014. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (http://creativecommons.org/licenses/by/3.0/).
DescriptionThe authors acknowledge the ERC (Advanced Researcher award-FUNCAT, CO2Chem) and King Saud University for funding and the EPSRC NMSSC in Swansea for mass spectrometric analyses. SPN is a Royal Society Wolfson Research Merit Award holder.
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