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The Assembly-Disassembly-Organization-Reassembly mechanism for 3D-2D-3D transformation of germanosilicate IWW zeolite

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dc.contributor.authorChlubná-Eliášová, Pavla
dc.contributor.authorTian, Yuyang
dc.contributor.authorPinar, Ana B.
dc.contributor.authorKubů, Martin
dc.contributor.authorČejka, Jiří
dc.contributor.authorMorris, Russell Edward
dc.date.accessioned2014-08-14T19:31:02Z
dc.date.available2014-08-14T19:31:02Z
dc.date.issued2014-07-01
dc.identifier118403513
dc.identifier54dc83af-e75a-4775-b49e-4eecb5ae3c12
dc.identifier000338023000041
dc.identifier.citationChlubná-Eliášová , P , Tian , Y , Pinar , A B , Kubů , M , Čejka , J & Morris , R E 2014 , ' The Assembly-Disassembly-Organization-Reassembly mechanism for 3D-2D-3D transformation of germanosilicate IWW zeolite ' , Angewandte Chemie , vol. 126 , no. 27 , pp. 7168–7172 . https://doi.org/10.1002/ange.201400600en
dc.identifier.issn0044-8249
dc.identifier.otherORCID: /0000-0001-7809-0315/work/69029134
dc.identifier.urihttps://hdl.handle.net/10023/5164
dc.descriptionThis research was part funded by EPSRC grant number EP/K025112/1. The article processing charge for this article was funded through the RCUK open access block grant.en
dc.description.abstractHydrolysis of germanosilicate zeolites with the IWW structure shows two different outcomes depending on the composition of the starting materials. Ge-rich IWW (Si/Ge=3.1) is disassembled into a layered material (IPC-5P), which can be reassembled into an almost pure silica IWW on treatment with diethoxydimethylsilane. Ge-poor IWW (Si/Ge=6.4) is not completely disassembled on hydrolysis, but retains some 3D connectivity. This structure can be reassembled into IWW by incorporation of Al to fill the defects left when the Ge is removed.
dc.format.extent554661
dc.language.isoeng
dc.relation.ispartofAngewandte Chemieen
dc.subjectADORen
dc.subjectFestkörperreaktionenen
dc.subjectGermanosilicateen
dc.subjectIWWen
dc.subjectZeolitheen
dc.subjectQD Chemistryen
dc.subject.lccQDen
dc.titleThe Assembly-Disassembly-Organization-Reassembly mechanism for 3D-2D-3D transformation of germanosilicate IWW zeoliteen
dc.typeJournal articleen
dc.contributor.sponsorEPSRCen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doi10.1002/ange.201400600
dc.description.statusPeer revieweden
dc.identifier.grantnumberEP/K025112/1en


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