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Sodium phenyldiselenophosphonate salts and Se-alkyl-O-alkylphenyl-phosphonodiselenoates and Se,Se '-dialkyl-O,O '-dialkyl-bis(phenylphosphonodiselenoate)s
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| dc.contributor.author | Hua, Guoxiong | |
| dc.contributor.author | Woollins, J. Derek | |
| dc.date.accessioned | 2014-08-11T14:31:01Z | |
| dc.date.available | 2014-08-11T14:31:01Z | |
| dc.date.issued | 2012-07-25 | |
| dc.identifier.citation | Hua , G & Woollins , J D 2012 , ' Sodium phenyldiselenophosphonate salts and Se-alkyl-O-alkylphenyl-phosphonodiselenoates and Se,Se '-dialkyl-O,O '-dialkyl-bis(phenylphosphonodiselenoate)s ' , Polyhedron , vol. 42 , no. 1 , pp. 190-195 . https://doi.org/10.1016/j.poly.2012.05.010 | en |
| dc.identifier.issn | 0277-5387 | |
| dc.identifier.other | PURE: 30482328 | |
| dc.identifier.other | PURE UUID: 49becb75-f15d-438d-9b6f-1c452d5eff6c | |
| dc.identifier.other | WOS: 000307152900027 | |
| dc.identifier.other | Scopus: 84863784246 | |
| dc.identifier.other | ORCID: /0000-0002-1498-9652/work/31779216 | |
| dc.identifier.uri | https://hdl.handle.net/10023/5105 | |
| dc.description | Funding: University of St Andrews | en |
| dc.description.abstract | The reaction of sodium alkoxides [(RONa)-O-1, R-1 = CH3, CH3CH2, (CH3)(2)CH and CH3CH2CH2] with 2,4-diphenyl-1,3-diselenadiphosphetane-2,4-diselenide [PhP(Se)(mu-Se)](2) (Woollins' reagent, WR) gave the non-symmetric sodium phenyldiselenophosphonate salts 1a-1d, the latter were further treated with haloalkanes [(RX)-X-2, R-2 = alkyl and aryl; X = Br, Cl and I] or dihaloalkanes [Br-(CH2)(n)-Br, n = 1-3 and BrCH2C6H4CH2Br-p] to afford a series of new Se-alkyl O-alkylphenylphosphonodiselenoate esters 2a-2k and Se,Se'-dialkyl-O,O'-dialkyl bis(phenylphosphonodiselenoate) esters 3a-3j in good to excellent yields. Crown Copyright (c) 2012 Published by Elsevier Ltd. All rights reserved. | |
| dc.format.extent | 6 | |
| dc.language.iso | eng | |
| dc.relation.ispartof | Polyhedron | en |
| dc.rights | © 2012 Published by Elsevier Ltd. All rights reserved. This is the author’s version of a work that was accepted for publication in Polyhedron. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Polyhedron, 42, 1, 25 July 2012 DOI 10.1016/j.poly.2012.05.010 | en |
| dc.subject | Woollins’ reagent | en |
| dc.subject | Phosphorus | en |
| dc.subject | Selenium | en |
| dc.subject | Sodium phenyldiselenophosphonate salts and Se-alkyl-O-alkylphenyl-phosphonodiselenoates and Se,Se '-dialkyl-O,O '-dialkyl | en |
| dc.subject | bis(phenylphosphonodiselenoate) esters | en |
| dc.subject | QD Chemistry | en |
| dc.subject.lcc | QD | en |
| dc.title | Sodium phenyldiselenophosphonate salts and Se-alkyl-O-alkylphenyl-phosphonodiselenoates and Se,Se '-dialkyl-O,O '-dialkyl-bis(phenylphosphonodiselenoate)s | en |
| dc.type | Journal article | en |
| dc.description.version | Postprint | en |
| dc.contributor.institution | University of St Andrews. School of Chemistry | en |
| dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
| dc.identifier.doi | https://doi.org/10.1016/j.poly.2012.05.010 | |
| dc.description.status | Peer reviewed | en |
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