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Sodium phenyldiselenophosphonate salts and Se-alkyl-O-alkylphenyl-phosphonodiselenoates and Se,Se '-dialkyl-O,O '-dialkyl-bis(phenylphosphonodiselenoate)s
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dc.contributor.author | Hua, Guoxiong | |
dc.contributor.author | Woollins, J. Derek | |
dc.date.accessioned | 2014-08-11T14:31:01Z | |
dc.date.available | 2014-08-11T14:31:01Z | |
dc.date.issued | 2012-07-25 | |
dc.identifier | 30482328 | |
dc.identifier | 49becb75-f15d-438d-9b6f-1c452d5eff6c | |
dc.identifier | 000307152900027 | |
dc.identifier | 84863784246 | |
dc.identifier.citation | Hua , G & Woollins , J D 2012 , ' Sodium phenyldiselenophosphonate salts and Se-alkyl-O-alkylphenyl-phosphonodiselenoates and Se,Se '-dialkyl-O,O '-dialkyl-bis(phenylphosphonodiselenoate)s ' , Polyhedron , vol. 42 , no. 1 , pp. 190-195 . https://doi.org/10.1016/j.poly.2012.05.010 | en |
dc.identifier.issn | 0277-5387 | |
dc.identifier.other | ORCID: /0000-0002-1498-9652/work/31779216 | |
dc.identifier.uri | https://hdl.handle.net/10023/5105 | |
dc.description | Funding: University of St Andrews | en |
dc.description.abstract | The reaction of sodium alkoxides [(RONa)-O-1, R-1 = CH3, CH3CH2, (CH3)(2)CH and CH3CH2CH2] with 2,4-diphenyl-1,3-diselenadiphosphetane-2,4-diselenide [PhP(Se)(mu-Se)](2) (Woollins' reagent, WR) gave the non-symmetric sodium phenyldiselenophosphonate salts 1a-1d, the latter were further treated with haloalkanes [(RX)-X-2, R-2 = alkyl and aryl; X = Br, Cl and I] or dihaloalkanes [Br-(CH2)(n)-Br, n = 1-3 and BrCH2C6H4CH2Br-p] to afford a series of new Se-alkyl O-alkylphenylphosphonodiselenoate esters 2a-2k and Se,Se'-dialkyl-O,O'-dialkyl bis(phenylphosphonodiselenoate) esters 3a-3j in good to excellent yields. Crown Copyright (c) 2012 Published by Elsevier Ltd. All rights reserved. | |
dc.format.extent | 6 | |
dc.format.extent | 581731 | |
dc.language.iso | eng | |
dc.relation.ispartof | Polyhedron | en |
dc.subject | Woollins’ reagent | en |
dc.subject | Phosphorus | en |
dc.subject | Selenium | en |
dc.subject | Sodium phenyldiselenophosphonate salts and Se-alkyl-O-alkylphenyl-phosphonodiselenoates and Se,Se '-dialkyl-O,O '-dialkyl | en |
dc.subject | bis(phenylphosphonodiselenoate) esters | en |
dc.subject | QD Chemistry | en |
dc.subject.lcc | QD | en |
dc.title | Sodium phenyldiselenophosphonate salts and Se-alkyl-O-alkylphenyl-phosphonodiselenoates and Se,Se '-dialkyl-O,O '-dialkyl-bis(phenylphosphonodiselenoate)s | en |
dc.type | Journal article | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | https://doi.org/10.1016/j.poly.2012.05.010 | |
dc.description.status | Peer reviewed | en |
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