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Silver(I) coordination complexes and extended networks assembled from S, Se, Te substituted acenaphthenes
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dc.contributor.author | Knight, Fergus R. | |
dc.contributor.author | Randall, Rebecca A. M. | |
dc.contributor.author | Wakefield, Lucy | |
dc.contributor.author | Slawin, Alexandra M. Z. | |
dc.contributor.author | Woollins, J. Derek | |
dc.date.accessioned | 2014-08-11T13:31:01Z | |
dc.date.available | 2014-08-11T13:31:01Z | |
dc.date.issued | 2013-01-07 | |
dc.identifier.citation | Knight , F R , Randall , R A M , Wakefield , L , Slawin , A M Z & Woollins , J D 2013 , ' Silver(I) coordination complexes and extended networks assembled from S, Se, Te substituted acenaphthenes ' , Dalton Transactions , vol. 42 , no. 1 , pp. 143-154 . https://doi.org/10.1039/c2dt31390a | en |
dc.identifier.issn | 1477-9226 | |
dc.identifier.other | PURE: 43111185 | |
dc.identifier.other | PURE UUID: fdd9d2db-b78c-4cdd-86c5-83323ac0742e | |
dc.identifier.other | WOS: 000312218100018 | |
dc.identifier.other | Scopus: 84870218228 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/56861729 | |
dc.identifier.other | ORCID: /0000-0002-1498-9652/work/31779207 | |
dc.identifier.uri | https://hdl.handle.net/10023/5100 | |
dc.description | The work in this project was supported by the Engineering and Physical Sciences Research Council (EPSRC). | en |
dc.description.abstract | Six related organo-chalconium silver(I) coordination complexes, including two examples of rare organo-tellurium-silver coordination, have been prepared and structurally characterised by X-ray crystallography. The series of 5-bromo-6-(phenylchalcogeno)acenaphthene ligands L1-L3 [Acenap(Br)(EPh)] (Acenap = acenaphthene-5,6-diyl; E = S, Se, Te) were independently treated with silver(I) salts (AgBF4, AgOTf). In order to keep the number of variables to a minimum, all reactions were carried out using a 1 : 1 ratio of Ag/L and run in dichloromethane. The nature of the donor atoms and the coordinating ability of the respective counter-anion affects the structural architecture of the final silver(I) complex, generating a monomeric dinuclear complex {[(AgBF4(L1)(2))(2)] 1}, monomeric, mononuclear, two-coordinate silver(I) complexes {[AgBF4(L)(2)] (2 L = L2; 3 L = L3)}, a monomeric three-coordinate silver(I) complex {[AgOTf(L2)(2)] 5}, a monomeric four-coordinate silver(I) complex {[AgOTf(L1)(3)] 4} and a 1D extended helical chain polymer {[AgOTf(L3)](n) 6}. The organic acenaphthene ligands L1-L3 all adopt the same ligation mode with the central silver atom (classical monodentate coordination), which employs a variety of coordination geometries (linear, trigonal planar, see-saw, tetrahedral). | |
dc.format.extent | 12 | |
dc.language.iso | eng | |
dc.relation.ispartof | Dalton Transactions | en |
dc.rights | © 2013. The Royal Society of Chemistry. This is an Accepted Manuscript of an article published in the Dalton Transactions on 7 January 2013, available online: http://pubs.rsc.org/en/Content/ArticleLanding/2013/DT/c2dt31390a#!divAbstract | en |
dc.subject | QD Chemistry | en |
dc.subject.lcc | QD | en |
dc.title | Silver(I) coordination complexes and extended networks assembled from S, Se, Te substituted acenaphthenes | en |
dc.type | Journal article | en |
dc.description.version | Postprint | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | https://doi.org/10.1039/c2dt31390a | |
dc.description.status | Peer reviewed | en |
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