Chemistry: Recent submissions
Now showing items 466-470 of 897
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The carbonylation of allylic halides
(University of St Andrews, 1997) - Thesis[RhCl(CO)(Pet₃)₂] or a compound prepared in situ from [Rh₂(OAc)₄] and Pet₃ have been shown to be active catalysts for the carbonylation of allylic halides under relatively mild conditions. This reaction is of considerable ... -
Novel group 9 catalysts for the carbonylation of methanol
(University of St Andrews, 1998) - ThesisThe carbonylation of methanol catalysed by Group 9 metals is the principle industrial route to acetic acid. It has been one of the most important applications of homogeneous catalysts for thirty years. In that time the ... -
The solubility of gases in aqueous alcohols
(University of St Andrews, 1974) - ThesisExtensive measurements have been made of the solubilities of the five gases helium, hydrogen, argon, oxygen, and carbon dioxide, in ethanol/water and in t-butanol/water mixtures over the whole of their concentration range, ... -
Synthesis of long-chain fatty acids and some derivatives
(University of St Andrews, 1975) - ThesisAn attempt has been made to compare anodic synthesis, malonation, and chain-extension with enamines as procedures for converting readily-available acids to higher homologues. Anodic synthesis was successfully employed to ... -
Synthetic, degradative, analytical and configurational studies of long chain epoxy and hydroxy acids
(University of St Andrews, 1958) - ThesisPart I. Synthetic studies. cis-Hydroxylation of Long-chain Olefins. The Woodward cis-hydroxylation procedure, involving the use of iodine and silver acetate in wet acetic acid, has been adapted and applied to the ...