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dc.contributor.authorHua, Guoxiong
dc.contributor.authorRandall, Rebecca A. M.
dc.contributor.authorSlawin, Alexandra M. Z.
dc.contributor.authorWoollins, J. Derek
dc.date.accessioned2014-08-11T12:01:00Z
dc.date.available2014-08-11T12:01:00Z
dc.date.issued2011-10
dc.identifier.citationHua , G , Randall , R A M , Slawin , A M Z & Woollins , J D 2011 , ' Ammonium Phenylphosphonamidodiselenoates and Phenylphosphonamidodi-selenoic Diamides from the Selenation of Primary and Secondary Amines ' , Zeitschrift für Anorganische und Allgemeine Chemie , vol. 637 , no. 12 , pp. 1800-1806 . https://doi.org/10.1002/zaac.201100257en
dc.identifier.issn0044-2313
dc.identifier.otherPURE: 16776620
dc.identifier.otherPURE UUID: a6d60f7c-d97f-47a1-b534-866cc3573f35
dc.identifier.otherWOS: 000296856300023
dc.identifier.otherScopus: 80054968743
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861349
dc.identifier.otherORCID: /0000-0002-1498-9652/work/31779227
dc.identifier.urihttp://hdl.handle.net/10023/5099
dc.descriptionThe authors are thankful to the University of St Andrews and the Engineering and Physical Science Research Council (EPSRC, U.K.) for financial support.en
dc.description.abstractBy reacting two equivalents of primary or secondary amines with 2,4-bis(phenyl)-1,3-diselenadiphosphetane-2,4-diselenide (Woollins' reagent) at room temperature a series of new ammonium phenylphosphonamidodiselenoates 1-7 have been obtained in good to excellent yields (70-99 %). The first metal complex of phenylphosphonamidodiselenoate, the complex of Cd2L4 (L = [Se2PPh(NCH(CH3)(2)](-)) (8) has been prepared from the reaction of diisopropylamine N-isopropyl-P-phenylphosphonamidodiselenoate with Cd(CH3COO)(2) in dichloromethane. Upon heating to 130 degrees C the ammonium phenylphosphonamidodiselenoates lose hydrogen selenide leading to the corresponding phenylphosphonamidodiselenoic diamides 9-11 in almost quantitative yields. The same products 9-11 can also be prepared directly from the reaction of primary amines with Woollins' reagent in refluxing toluene. Three representative X-ray structures are described.
dc.format.extent7
dc.language.isoeng
dc.relation.ispartofZeitschrift für Anorganische und Allgemeine Chemieen
dc.rights© 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This is an Accepted Manuscript of an article published in Zeitschrift für anorganische und allgemeine Chemie on 25 August 2011, available online: http://onlinelibrary.wiley.com/doi/10.1002/zaac.201100257/pdfen
dc.subjectWoollins' reagenten
dc.subjectAminesen
dc.subjectAmmonium phenylphosphonamidodiselenoatesen
dc.subjectPhenylphosphonamidodiselenoic diamidesen
dc.subjectX-ray diffractionen
dc.subjectPhosphor-1,1-dithiolato metal-complexesen
dc.subjectSupramolecular associationsen
dc.subjectCoordination chemistryen
dc.subjectStereochemical aspectsen
dc.subjectMolecular-structuresen
dc.subjectOrganic-synthesisen
dc.subjectSeleniumen
dc.subjectOrganoseleniumen
dc.subjectPatternsen
dc.subjectQD Chemistryen
dc.subject.lccQDen
dc.titleAmmonium Phenylphosphonamidodiselenoates and Phenylphosphonamidodi-selenoic Diamides from the Selenation of Primary and Secondary Aminesen
dc.typeJournal articleen
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1002/zaac.201100257
dc.description.statusPeer revieweden


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