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Ammonium Phenylphosphonamidodiselenoates and Phenylphosphonamidodi-selenoic Diamides from the Selenation of Primary and Secondary Amines
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dc.contributor.author | Hua, Guoxiong | |
dc.contributor.author | Randall, Rebecca A. M. | |
dc.contributor.author | Slawin, Alexandra M. Z. | |
dc.contributor.author | Woollins, J. Derek | |
dc.date.accessioned | 2014-08-11T12:01:00Z | |
dc.date.available | 2014-08-11T12:01:00Z | |
dc.date.issued | 2011-10 | |
dc.identifier.citation | Hua , G , Randall , R A M , Slawin , A M Z & Woollins , J D 2011 , ' Ammonium Phenylphosphonamidodiselenoates and Phenylphosphonamidodi-selenoic Diamides from the Selenation of Primary and Secondary Amines ' , Zeitschrift für Anorganische und Allgemeine Chemie , vol. 637 , no. 12 , pp. 1800-1806 . https://doi.org/10.1002/zaac.201100257 | en |
dc.identifier.issn | 0044-2313 | |
dc.identifier.other | PURE: 16776620 | |
dc.identifier.other | PURE UUID: a6d60f7c-d97f-47a1-b534-866cc3573f35 | |
dc.identifier.other | WOS: 000296856300023 | |
dc.identifier.other | Scopus: 80054968743 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/56861349 | |
dc.identifier.other | ORCID: /0000-0002-1498-9652/work/31779227 | |
dc.identifier.uri | https://hdl.handle.net/10023/5099 | |
dc.description | The authors are thankful to the University of St Andrews and the Engineering and Physical Science Research Council (EPSRC, U.K.) for financial support. | en |
dc.description.abstract | By reacting two equivalents of primary or secondary amines with 2,4-bis(phenyl)-1,3-diselenadiphosphetane-2,4-diselenide (Woollins' reagent) at room temperature a series of new ammonium phenylphosphonamidodiselenoates 1-7 have been obtained in good to excellent yields (70-99 %). The first metal complex of phenylphosphonamidodiselenoate, the complex of Cd2L4 (L = [Se2PPh(NCH(CH3)(2)](-)) (8) has been prepared from the reaction of diisopropylamine N-isopropyl-P-phenylphosphonamidodiselenoate with Cd(CH3COO)(2) in dichloromethane. Upon heating to 130 degrees C the ammonium phenylphosphonamidodiselenoates lose hydrogen selenide leading to the corresponding phenylphosphonamidodiselenoic diamides 9-11 in almost quantitative yields. The same products 9-11 can also be prepared directly from the reaction of primary amines with Woollins' reagent in refluxing toluene. Three representative X-ray structures are described. | |
dc.format.extent | 7 | |
dc.language.iso | eng | |
dc.relation.ispartof | Zeitschrift für Anorganische und Allgemeine Chemie | en |
dc.rights | © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This is an Accepted Manuscript of an article published in Zeitschrift für anorganische und allgemeine Chemie on 25 August 2011, available online: http://onlinelibrary.wiley.com/doi/10.1002/zaac.201100257/pdf | en |
dc.subject | Woollins' reagent | en |
dc.subject | Amines | en |
dc.subject | Ammonium phenylphosphonamidodiselenoates | en |
dc.subject | Phenylphosphonamidodiselenoic diamides | en |
dc.subject | X-ray diffraction | en |
dc.subject | Phosphor-1,1-dithiolato metal-complexes | en |
dc.subject | Supramolecular associations | en |
dc.subject | Coordination chemistry | en |
dc.subject | Stereochemical aspects | en |
dc.subject | Molecular-structures | en |
dc.subject | Organic-synthesis | en |
dc.subject | Selenium | en |
dc.subject | Organoselenium | en |
dc.subject | Patterns | en |
dc.subject | QD Chemistry | en |
dc.subject.lcc | QD | en |
dc.title | Ammonium Phenylphosphonamidodiselenoates and Phenylphosphonamidodi-selenoic Diamides from the Selenation of Primary and Secondary Amines | en |
dc.type | Journal article | en |
dc.description.version | Postprint | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | https://doi.org/10.1002/zaac.201100257 | |
dc.description.status | Peer reviewed | en |
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