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The Synthesis of [{n-Bu2Sn(S2N2)}2] and its use in the preparation of Organometallic Iridium Sulfur Nitrogen Complexes
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dc.contributor.author | Aucott, SM | |
dc.contributor.author | Slawin, Alexandra Martha Zoya | |
dc.contributor.author | Woollins, John Derek | |
dc.date.accessioned | 2014-07-01T09:31:00Z | |
dc.date.available | 2014-07-01T09:31:00Z | |
dc.date.issued | 2002-11 | |
dc.identifier | 155336 | |
dc.identifier | f7c13e54-de55-4f34-ba10-e2032f6f176f | |
dc.identifier | 000179703800016 | |
dc.identifier | 0036904344 | |
dc.identifier.citation | Aucott , SM , Slawin , A M Z & Woollins , J D 2002 , ' The Synthesis of [{ n -Bu 2 Sn(S 2 N 2 )} 2 ] and its use in the preparation of Organometallic Iridium Sulfur Nitrogen Complexes ' , Candian Journal of Chemistry , vol. 80 , pp. 1481-1487 . https://doi.org/10.1139/V02-085 | en |
dc.identifier.issn | 1480-3291 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/56861834 | |
dc.identifier.other | ORCID: /0000-0002-1498-9652/work/31779293 | |
dc.identifier.uri | https://hdl.handle.net/10023/4934 | |
dc.description.abstract | The addition of [n-Bu2SnCl2] to a solution of [S4N3][Cl] in liquid ammonia gave after extraction of the dry reaction mixture the new tin disulfur dinitrido compound [{n-Bu2Sn(S2N2)}(2)] (1). Reaction of [{n-Bu2Sn(S2N2)}(2)] (1) with the pentamethylcyclopentadienyl (Cp*) iridium derivatives [{IrCl(mu-Cl)(eta(5)-C5Me5)}(2)] or [(eta(5)-C5Me5)IrCl2(PPh3)] gave different products, which were dependent on the reactant ratios. A 1:1 reaction between 1 and [{IrCl(mu-Cl)(eta(5)-C5Me5)}(2)] gave only [(eta(5)-C5Me5)Ir(S2N2)] (2) in moderate yield; the same product in higher yield was obtained from a 2:1 reaction between 1 and [(eta(5)-C5Me5)IrCl2(PPh3)]. Reaction of 1 and [(eta(5)-C5Me5)(2)IrCl2(PPh3)] (1:1 molar ratio) in the presence of NH4[PF6] gave the unusual bimetallic species [(eta(5)-C5Me5)IrCl(PPh3)(S2N2)Ir(eta(5)-C5Me5)][PF6] (3). The X-ray crystal structures of 1, 2, and 3 are reported. | |
dc.format.extent | 7 | |
dc.format.extent | 254464 | |
dc.language.iso | eng | |
dc.relation.ispartof | Candian Journal of Chemistry | en |
dc.subject | Liquid ammonia | en |
dc.subject | Tin sulfur | en |
dc.subject | Nitrogen reagent | en |
dc.subject | Metathesis | en |
dc.subject | Sulfur-nitrogen metallacycle | en |
dc.subject | Iridium complexes | en |
dc.subject | Coordination chemistry | en |
dc.subject | Products | en |
dc.subject | PD | en |
dc.subject | QD Chemistry | en |
dc.subject.lcc | QD | en |
dc.title | The Synthesis of [{n-Bu2Sn(S2N2)}2] and its use in the preparation of Organometallic Iridium Sulfur Nitrogen Complexes | en |
dc.type | Journal article | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | 10.1139/V02-085 | |
dc.description.status | Peer reviewed | en |
dc.identifier.url | http://www.scopus.com/inward/record.url?scp=0036904344&partnerID=8YFLogxK | en |
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