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dc.contributor.authorAucott, SM
dc.contributor.authorSlawin, Alexandra Martha Zoya
dc.contributor.authorWoollins, John Derek
dc.date.accessioned2014-07-01T09:31:00Z
dc.date.available2014-07-01T09:31:00Z
dc.date.issued2002-11
dc.identifier.citationAucott , SM , Slawin , A M Z & Woollins , J D 2002 , ' The Synthesis of [{ n -Bu 2 Sn(S 2 N 2 )} 2 ] and its use in the preparation of Organometallic Iridium Sulfur Nitrogen Complexes ' Candian Journal of Chemistry , vol. 80 , pp. 1481-1487 . https://doi.org/10.1139/V02-085en
dc.identifier.issn1480-3291
dc.identifier.otherPURE: 155336
dc.identifier.otherPURE UUID: f7c13e54-de55-4f34-ba10-e2032f6f176f
dc.identifier.otherWOS: 000179703800016
dc.identifier.otherScopus: 0036904344
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861834
dc.identifier.urihttp://hdl.handle.net/10023/4934
dc.description.abstractThe addition of [n-Bu2SnCl2] to a solution of [S4N3][Cl] in liquid ammonia gave after extraction of the dry reaction mixture the new tin disulfur dinitrido compound [{n-Bu2Sn(S2N2)}(2)] (1). Reaction of [{n-Bu2Sn(S2N2)}(2)] (1) with the pentamethylcyclopentadienyl (Cp*) iridium derivatives [{IrCl(mu-Cl)(eta(5)-C5Me5)}(2)] or [(eta(5)-C5Me5)IrCl2(PPh3)] gave different products, which were dependent on the reactant ratios. A 1:1 reaction between 1 and [{IrCl(mu-Cl)(eta(5)-C5Me5)}(2)] gave only [(eta(5)-C5Me5)Ir(S2N2)] (2) in moderate yield; the same product in higher yield was obtained from a 2:1 reaction between 1 and [(eta(5)-C5Me5)IrCl2(PPh3)]. Reaction of 1 and [(eta(5)-C5Me5)(2)IrCl2(PPh3)] (1:1 molar ratio) in the presence of NH4[PF6] gave the unusual bimetallic species [(eta(5)-C5Me5)IrCl(PPh3)(S2N2)Ir(eta(5)-C5Me5)][PF6] (3). The X-ray crystal structures of 1, 2, and 3 are reported.
dc.format.extent7
dc.language.isoeng
dc.relation.ispartofCandian Journal of Chemistryen
dc.rights© 2002. Canadian Science Publishing.en
dc.subjectLiquid ammoniaen
dc.subjectTin sulfuren
dc.subjectNitrogen reagenten
dc.subjectMetathesisen
dc.subjectSulfur-nitrogen metallacycleen
dc.subjectIridium complexesen
dc.subjectCoordination chemistryen
dc.subjectProductsen
dc.subjectPDen
dc.subjectQD Chemistryen
dc.subject.lccQDen
dc.titleThe Synthesis of [{n-Bu2Sn(S2N2)}2] and its use in the preparation of Organometallic Iridium Sulfur Nitrogen Complexesen
dc.typeJournal articleen
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1139/V02-085
dc.description.statusPeer revieweden
dc.identifier.urlhttp://www.scopus.com/inward/record.url?scp=0036904344&partnerID=8YFLogxK


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