Show simple item record

Files in this item

Thumbnail

Item metadata

dc.contributor.authorHua, Guoxiong
dc.contributor.authorDu, Junyi
dc.contributor.authorSlawin, Alexandra M. Z.
dc.contributor.authorWoollins, J. Derek
dc.date.accessioned2014-06-30T23:01:42Z
dc.date.available2014-06-30T23:01:42Z
dc.date.issued2013-07-15
dc.identifier.citationHua , G , Du , J , Slawin , A M Z & Woollins , J D 2013 , ' Fluorinated Phosphorus-Selenium Heteroatom Compounds : Phenylphosphonofluorodiselenoic Salts, Adducts, and Esters ' , Inorganic Chemistry , vol. 52 , no. 14 , pp. 8214-8217 . https://doi.org/10.1021/ic400612wen
dc.identifier.issn0020-1669
dc.identifier.otherPURE: 112010116
dc.identifier.otherPURE UUID: debe8acd-bc90-4af4-8c96-fe3dda11d592
dc.identifier.otherWOS: 000322087100045
dc.identifier.otherScopus: 84880255568
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861501
dc.identifier.otherORCID: /0000-0002-1498-9652/work/31779203
dc.identifier.urihttp://hdl.handle.net/10023/4931
dc.description.abstract2,4-Bis(phenyl)-1,3-diselenadiphosphetane-2,4-diselenide, [PhP(Se)(mu-Se)](2), Woollins' reagent (WR), reacts with dry KF or tetrabutylammonium fluoride (TBAF) at room temperature generating the corresponding potassium and tetrabutylammonium phenyldiselenofluorophosphinates 1 and 2 in almost quantitative yields. Treating 1 with equimolar amounts of tetraphenylphosphonium chloride or 1,3-dimesityl-1H-imidazol-3-ium chloride in THF at room temperature afforded the corresponding organic adducts 3 and 4 in 90% and 87% yields. Reaction of 1 with mono- and dihalogenated alkanes gave a series of esters of phenylphosphonofluoridodiselenoates 5-8 and 9 in 79-93% yields. Two representative crystal structures are reported.
dc.format.extent4
dc.language.isoeng
dc.relation.ispartofInorganic Chemistryen
dc.rights© 2013, American Chemical Society. This document is the Accepted Manuscript version of a Published Work that appeared in final form in Inorganic Chemistry after peer review and technical editing by the publisher. To access the final edited and published work see DOI: 10.1021/ic400612wen
dc.subjectWoollins' reagenten
dc.subjectEfficient synthesisen
dc.subjectAnalogsen
dc.subjectHeterocyclesen
dc.subjectAcetylcholinesteraseen
dc.subjectPhosphorofluoridateen
dc.subjectSelenationen
dc.subjectQD Chemistryen
dc.subject.lccQDen
dc.titleFluorinated Phosphorus-Selenium Heteroatom Compounds : Phenylphosphonofluorodiselenoic Salts, Adducts, and Estersen
dc.typeJournal articleen
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1021/ic400612w
dc.description.statusPeer revieweden
dc.date.embargoedUntil2014-07-01


This item appears in the following Collection(s)

Show simple item record