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dc.contributor.authorHamilton, Neil G.
dc.contributor.authorWarringham, Robbie
dc.contributor.authorSilverwood, Ian P.
dc.contributor.authorKapitán, Josef
dc.contributor.authorHecht, Lutz
dc.contributor.authorWebb, Paul B.
dc.contributor.authorTooze, Robert P.
dc.contributor.authorZhou, Wuzong
dc.contributor.authorFrost, Christopher D.
dc.contributor.authorParker, Stewart F.
dc.contributor.authorLennon, David
dc.date.accessioned2014-05-13T14:01:02Z
dc.date.available2014-05-13T14:01:02Z
dc.date.issued2014-04
dc.identifier.citationHamilton , N G , Warringham , R , Silverwood , I P , Kapitán , J , Hecht , L , Webb , P B , Tooze , R P , Zhou , W , Frost , C D , Parker , S F & Lennon , D 2014 , ' The application of inelastic neutron scattering to investigate CO hydrogenation over an iron Fischer–Tropsch synthesis catalyst ' , Journal of Catalysis , vol. 312 , pp. 221-231 . https://doi.org/10.1016/j.jcat.2014.02.004en
dc.identifier.issn0021-9517
dc.identifier.otherPURE: 118163973
dc.identifier.otherPURE UUID: a61c3a7c-63f0-48bd-ad9c-8d682fd932ba
dc.identifier.otherRIS: urn:812FE781756F3C9DF958E69A2078E708
dc.identifier.otherScopus: 84896129306
dc.identifier.otherORCID: /0000-0001-9752-7076/work/58055096
dc.identifier.otherWOS: 000335111300022
dc.identifier.otherORCID: /0000-0003-2532-344X/work/67167805
dc.identifier.urihttp://hdl.handle.net/10023/4776
dc.descriptionFunding: Sasol Technology UK Ltd., STFC (CCLRC) and the University of Glasgow- provision of studentships (NGH and RW). The development of INS sample cells and associated sample handling capability was supported by funding from the EPSRC (Grant Number EP/E028861/1).en
dc.description.abstractAn iron Fischer–Tropsch (F–T) catalyst has been prepared and evaluated using CO hydrogenation at 623 and 723 K as a test reaction. Micro-reactor measurements establish reaction profiles. The reaction is then scaled up to enable inelastic neutron scattering (INS) measurements of the catalyst to be acquired. The INS spectra (200–4000 cm-1) are characterised by a combination of hydrocarbon moieties and hydroxyl groups. Whereas the low temperature sample is characterised by an aliphatic overlayer, the hydrocarbon features of the high temperature sample are attributed to partially hydrogenated polycyclic aromatic compounds. The catalyst is further characterised by a combination of temperature-programmed oxidation, powder X-ray diffraction, Raman scattering and transmission electron microscopy. This series of measurements is combined to propose a model for the composition of the catalyst as it progresses from the precursor state to steady-state operation. The work features some of the challenges associated with using INS to characterise heterogeneously catalysed reactions systems.
dc.format.extent11
dc.language.isoeng
dc.relation.ispartofJournal of Catalysisen
dc.rights© 2014 Elsevier Inc. All rights reserved. Published open access.en
dc.subjectFischer–Tropsch synthesisen
dc.subjectIron catalysten
dc.subjectCO hydrogenationen
dc.subjectInelastic neutron scatteringen
dc.subjectQD Chemistryen
dc.subject.lccQDen
dc.titleThe application of inelastic neutron scattering to investigate CO hydrogenation over an iron Fischer–Tropsch synthesis catalysten
dc.typeJournal articleen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1016/j.jcat.2014.02.004
dc.description.statusPeer revieweden
dc.identifier.urlhttp://www.sciencedirect.com/science/article/pii/S0021951714000438en


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