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Phenyl(2,4,5-triphenylcyclopenta-1,4-dien-1-yl)methanone

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Date
07/2011
Author
Cordes, David B.
Hua, Guoxiong
Slawin, Alexandra M. Z.
Woollins, J. Derek
Keywords
QD Chemistry
Metadata
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Abstract
The title compound, C30H22O, does not form face-to-face pi-pi interactions despite the presence of four phenyl rings within the compound. Instead weak C-H center dot center dot center dot pi interactions occur between adjacent molecules, with C center dot center dot center dot C contact distances in the range 3.633 (4)-3.974 (4) angstrom. The ketone O atom also takes part in a weak C-H center dot center dot center dot O interaction. The three pendant phenyl rings are twisted relative to the central cyclopentadiene ring by 17.82 (17), 29.63 (14) and 61.57 (9)degrees, while the phenylmethanone is nearly orthogonal, the angle between planes being 87.77 (9)degrees.
Citation
Cordes , D B , Hua , G , Slawin , A M Z & Woollins , J D 2011 , ' Phenyl(2,4,5-triphenylcyclopenta-1,4-dien-1-yl)methanone ' , Acta Crystallographica. Section E, Structure reports online , vol. 67 , o1718 . https://doi.org/10.1107/S1600536811022902
Publication
Acta Crystallographica. Section E, Structure reports online
Status
Peer reviewed
DOI
https://doi.org/10.1107/S1600536811022902
ISSN
1600-5368
Type
Journal article
Rights
(c) The Author(s) 2011.
Description
Funding: University of St Andrews and the EPSRC, UK.
Collections
  • University of St Andrews Research
URI
http://hdl.handle.net/10023/4704

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