Files in this item
The first organocatalytic carbonyl-ene reaction : isomerisation-free C-C bond formations catalysed by H-bonding thio-ureas
Item metadata
dc.contributor.author | Clarke, Matthew L. | |
dc.contributor.author | Jones, Charlotte E. S. | |
dc.contributor.author | France, Marcia B. | |
dc.date.accessioned | 2013-12-05T11:31:01Z | |
dc.date.available | 2013-12-05T11:31:01Z | |
dc.date.issued | 2007-09-14 | |
dc.identifier | 623855 | |
dc.identifier | 3f93b7d3-d54a-4f89-97ed-64b7fcb2e02a | |
dc.identifier | 000252525900001 | |
dc.identifier | 38149081322 | |
dc.identifier.citation | Clarke , M L , Jones , C E S & France , M B 2007 , ' The first organocatalytic carbonyl-ene reaction : isomerisation-free C-C bond formations catalysed by H-bonding thio-ureas ' , Beilstein Journal of Organic Chemistry , vol. 3 , 24 . https://doi.org/10.1186/1860-5397-3-24 | en |
dc.identifier.other | ORCID: /0000-0002-2444-1244/work/59464630 | |
dc.identifier.uri | https://hdl.handle.net/10023/4267 | |
dc.description.abstract | Intramolecular carbonyl ene reactions of highly activated enophiles can be catalysed by H-bonding thio-ureas to give tertiary alcohols in high yields without extensive isomerisation side products. An asymmetric variant of this reaction was realised using a chiral thiourea but was limited by low enantioselectivity (up to 33% e. e.) and low turnover frequencies. | |
dc.format.extent | 4 | |
dc.format.extent | 206664 | |
dc.language.iso | eng | |
dc.relation.ispartof | Beilstein Journal of Organic Chemistry | en |
dc.subject | ASYMMETRIC CATALYSIS | en |
dc.subject | COMPLEXES | en |
dc.subject | ACIDS | en |
dc.subject | QD Chemistry | en |
dc.subject.lcc | QD | en |
dc.title | The first organocatalytic carbonyl-ene reaction : isomerisation-free C-C bond formations catalysed by H-bonding thio-ureas | en |
dc.type | Journal article | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | 10.1186/1860-5397-3-24 | |
dc.description.status | Peer reviewed | en |
dc.identifier.url | http://www.scopus.com/inward/record.url?scp=38149081322&partnerID=8YFLogxK | en |
This item appears in the following Collection(s)
Items in the St Andrews Research Repository are protected by copyright, with all rights reserved, unless otherwise indicated.