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Backbone tuning in indenylidene-ruthenium complexes bearing an unsaturated N-heterocyclic carbene
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dc.contributor.author | Urbina-Blanco, Cesar A. | |
dc.contributor.author | Bantreil, Xavier | |
dc.contributor.author | Clavier, Herve | |
dc.contributor.author | Slawin, Alexandra M. Z. | |
dc.contributor.author | Nolan, Steven P. | |
dc.date.accessioned | 2013-12-04T15:31:03Z | |
dc.date.available | 2013-12-04T15:31:03Z | |
dc.date.issued | 2010-11 | |
dc.identifier | 5496074 | |
dc.identifier | 0d21a259-5a12-4349-bf0c-c8e3f2cbe211 | |
dc.identifier | 000284527400005 | |
dc.identifier | 78751518951 | |
dc.identifier.citation | Urbina-Blanco , C A , Bantreil , X , Clavier , H , Slawin , A M Z & Nolan , S P 2010 , ' Backbone tuning in indenylidene-ruthenium complexes bearing an unsaturated N-heterocyclic carbene ' , Beilstein Journal of Organic Chemistry , vol. 6 , pp. 1120-1126 . https://doi.org/10.3762/bjoc.6.128 | en |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/56861702 | |
dc.identifier.uri | https://hdl.handle.net/10023/4262 | |
dc.description.abstract | The steric and electronic influence of backbone substitution in IMes-based (IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene) N-heterocyclic carbenes (NHC) was probed by synthesizing the [RhCl(CO)(2)(NHC)] series of complexes to quantify experimentally the Tolman electronic parameter (electronic) and the percent buried volume (%V-bur, steric) parameters. The corresponding ruthenium-indenylidene complexes were also synthesized and tested in benchmark metathesis transformations to establish possible correlations between reactivity and NHC electronic and steric parameters. | |
dc.format.extent | 7 | |
dc.format.extent | 363794 | |
dc.language.iso | eng | |
dc.relation.ispartof | Beilstein Journal of Organic Chemistry | en |
dc.subject | N-heterocyclic carbene | en |
dc.subject | Olefin metathesis | en |
dc.subject | Percent buried volume | en |
dc.subject | Ruthenium-indenylidene | en |
dc.subject | Tolman electronic parameter | en |
dc.subject | QD Chemistry | en |
dc.subject.lcc | QD | en |
dc.title | Backbone tuning in indenylidene-ruthenium complexes bearing an unsaturated N-heterocyclic carbene | en |
dc.type | Journal article | en |
dc.contributor.sponsor | EPSRC | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | 10.3762/bjoc.6.128 | |
dc.description.status | Peer reviewed | en |
dc.identifier.grantnumber | EP/J011053/1 | en |
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