Files in this item
An ionothermally prepared S=1/2 vanadium oxyfluoride kagome lattice
Item metadata
dc.contributor.author | Himeur, Farida Himeur | |
dc.contributor.author | Aldous, David William | |
dc.contributor.author | Goff, Richard John | |
dc.contributor.author | Slawin, Alexandra Martha Zoya | |
dc.contributor.author | Attfield, J. Paul | |
dc.contributor.author | Morris, Russell Edward | |
dc.contributor.author | Lightfoot, Philip | |
dc.date.accessioned | 2013-06-14T09:31:01Z | |
dc.date.available | 2013-06-14T09:31:01Z | |
dc.date.issued | 2011-10 | |
dc.identifier.citation | Himeur , F H , Aldous , D W , Goff , R J , Slawin , A M Z , Attfield , J P , Morris , R E & Lightfoot , P 2011 , ' An ionothermally prepared S=1/2 vanadium oxyfluoride kagome lattice ' , Nature Chemistry , vol. 3 , no. 10 , pp. 801-806 . https://doi.org/10.1038/NCHEM.1129 | en |
dc.identifier.issn | 1755-4330 | |
dc.identifier.other | PURE: 16811221 | |
dc.identifier.other | PURE UUID: b606a95e-be0c-4376-b44c-ded4007f2736 | |
dc.identifier.other | WOS: 000295157200014 | |
dc.identifier.other | Scopus: 80053221152 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/56861350 | |
dc.identifier.other | ORCID: /0000-0001-7048-3982/work/59464408 | |
dc.identifier.other | ORCID: /0000-0001-7809-0315/work/61622057 | |
dc.identifier.uri | https://hdl.handle.net/10023/3699 | |
dc.description.abstract | Frustrated magnetic lattices offer the possibility of many exotic ground states that are of great fundamental importance. Of particular significance is the hunt for frustrated spin-1/2 networks as candidates for quantum spin liquids, which would have exciting and unusual magnetic properties at low temperatures. The few reported candidate materials have all been based on d9 ions. Here, we report the ionothermal synthesis of [NH4]2[C7H14N][V7O6F18], an inorganic-organic hybrid solid that contains a S = 1/2 kagome network of d1 V4+ ions. The compound exhibits a high degree of magnetic frustration, with significant antiferromagnetic interactions but no long-range magnetic order or spin-freezing above 2 K, and appears to be an excellent candidate for realizing a quantum spin liquid ground state in a spin-1/2 kagome network. | |
dc.format.extent | 6 | |
dc.language.iso | eng | |
dc.relation.ispartof | Nature Chemistry | en |
dc.rights | Copyright 2011, the Authors. This is an author version of this work deposited in accordance with publisher policy. | en |
dc.subject | Frustrated magnets | en |
dc.subject | Coordination polymers | en |
dc.subject | Ionic liquids | en |
dc.subject | Temperature | en |
dc.subject | Pyrochlore | en |
dc.subject | Frameworks | en |
dc.subject | Induction | en |
dc.subject | Chemistry | en |
dc.subject | Zeolites | en |
dc.subject | Template | en |
dc.subject | QD Chemistry | en |
dc.subject.lcc | QD | en |
dc.title | An ionothermally prepared S=1/2 vanadium oxyfluoride kagome lattice | en |
dc.type | Journal article | en |
dc.contributor.sponsor | EPSRC | en |
dc.contributor.sponsor | EPSRC | en |
dc.description.version | Preprint | en |
dc.description.version | Postprint | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | https://doi.org/10.1038/NCHEM.1129 | |
dc.description.status | Peer reviewed | en |
dc.identifier.grantnumber | EP/F021925/1 | en |
dc.identifier.grantnumber | EP/F055722/1 | en |
This item appears in the following Collection(s)
Items in the St Andrews Research Repository are protected by copyright, with all rights reserved, unless otherwise indicated.