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dc.contributor.authorHimeur, Farida Himeur
dc.contributor.authorAldous, David William
dc.contributor.authorGoff, Richard John
dc.contributor.authorSlawin, Alexandra Martha Zoya
dc.contributor.authorAttfield, J. Paul
dc.contributor.authorMorris, Russell Edward
dc.contributor.authorLightfoot, Philip
dc.date.accessioned2013-06-14T09:31:01Z
dc.date.available2013-06-14T09:31:01Z
dc.date.issued2011-10
dc.identifier.citationHimeur , F H , Aldous , D W , Goff , R J , Slawin , A M Z , Attfield , J P , Morris , R E & Lightfoot , P 2011 , ' An ionothermally prepared S=1/2 vanadium oxyfluoride kagome lattice ' , Nature Chemistry , vol. 3 , no. 10 , pp. 801-806 . https://doi.org/10.1038/NCHEM.1129en
dc.identifier.issn1755-4330
dc.identifier.otherPURE: 16811221
dc.identifier.otherPURE UUID: b606a95e-be0c-4376-b44c-ded4007f2736
dc.identifier.otherWOS: 000295157200014
dc.identifier.otherScopus: 80053221152
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861350
dc.identifier.otherORCID: /0000-0001-7048-3982/work/59464408
dc.identifier.otherORCID: /0000-0001-7809-0315/work/61622057
dc.identifier.urihttp://hdl.handle.net/10023/3699
dc.description.abstractFrustrated magnetic lattices offer the possibility of many exotic ground states that are of great fundamental importance. Of particular significance is the hunt for frustrated spin-1/2 networks as candidates for quantum spin liquids, which would have exciting and unusual magnetic properties at low temperatures. The few reported candidate materials have all been based on d9 ions. Here, we report the ionothermal synthesis of [NH4]2[C7H14N][V7O6F18], an inorganic-organic hybrid solid that contains a S = 1/2 kagome network of d1 V4+ ions. The compound exhibits a high degree of magnetic frustration, with significant antiferromagnetic interactions but no long-range magnetic order or spin-freezing above 2 K, and appears to be an excellent candidate for realizing a quantum spin liquid ground state in a spin-1/2 kagome network.
dc.format.extent6
dc.language.isoeng
dc.relation.ispartofNature Chemistryen
dc.rightsCopyright 2011, the Authors. This is an author version of this work deposited in accordance with publisher policy.en
dc.subjectFrustrated magnetsen
dc.subjectCoordination polymersen
dc.subjectIonic liquidsen
dc.subjectTemperatureen
dc.subjectPyrochloreen
dc.subjectFrameworksen
dc.subjectInductionen
dc.subjectChemistryen
dc.subjectZeolitesen
dc.subjectTemplateen
dc.subjectQD Chemistryen
dc.subject.lccQDen
dc.titleAn ionothermally prepared S=1/2 vanadium oxyfluoride kagome latticeen
dc.typeJournal articleen
dc.description.versionPreprinten
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1038/NCHEM.1129
dc.description.statusPeer revieweden


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