Show simple item record

Files in this item

Thumbnail

Item metadata

dc.contributor.advisorBruce, Peter G.
dc.contributor.authorDrewett, Nicholas E.
dc.coverage.spatial198en_US
dc.date.accessioned2013-05-08T09:07:42Z
dc.date.available2013-05-08T09:07:42Z
dc.date.issued2013-06-26
dc.identifieruk.bl.ethos.572728 
dc.identifier.urihttp://hdl.handle.net/10023/3513
dc.description.abstractThis thesis investigates several approaches to the development of high-performance batteries. A general background to the field and an introduction to the experimental methods used are given in Chapters 1 and 2 respectively. Chapter 3 presents a study of ordered and disordered LiNi₀.₅Mn₁.₅O₄ materials produced using an optimised resorcinol-formaldehyde gel (R-F gel) synthetic technique. Both materials exhibited good electrochemical properties and minimal side reaction with the electrolyte. Structural analyses of the materials in various states of discharge and charge were undertaken, and from these the charge / discharge processes were elucidated. In chapter 4 R-F gel synthesised Li(Ni₁/₃Mn₁/₃Co₁/₃)O₂ is studied and found to exhibit a high degree of structural stability on cycling, as well as excellent capacity, cyclability and rate capability. Photoelectron spectroscopy studies revealed that the R-F gel derived particles have highly stable surfaces. A discussion of the results and their significance, with particular regard to the outstanding electrochemical performance observed, is also presented. Chapter 5 sets out an investigation into the nature of R-F gel synthesised 0.5Li₂MnO₃:0.5LiNi₁/₃Mn₁/₃Co₁/₃O₂. The electrochemical data revealed that, after an initial activation stage, the R-F gel derived material exhibited a high capacity, good cyclability and exceptional rate capability. This chapter also considers some initial structural investigations and the electrochemical processes occurring on charge. In chapter 6 the use of ether-based electrolytes, combined with various cathode materials, in lithium-oxygen batteries is examined. The formation of decomposition products was observed, and a scheme suggesting probable reaction pathways is given. It was noted that significant quantities of the desired discharge product, lithium peroxide, were formed on the 1st cycle discharge, implying some electrolyte / cathode combinations do demonstrate a degree of stability. A summary of the results and a discussion of their significance are also included.en_US
dc.language.isoenen_US
dc.publisherUniversity of St Andrews
dc.subjectLi-ion batteriesen_US
dc.subjectCathodesen_US
dc.subjectLithium airen_US
dc.subjectCyclabilityen_US
dc.subject.lccTK2945.L58D8
dc.subject.lcshLithium ion batteriesen_US
dc.subject.lcshCathodes--Materialsen_US
dc.titleNovel routes to high performance lithium-ion batteriesen_US
dc.typeThesisen_US
dc.type.qualificationlevelDoctoralen_US
dc.type.qualificationnamePhD Doctor of Philosophyen_US
dc.publisher.institutionThe University of St Andrewsen_US
dc.rights.embargodatePrint and electronic copy restricted until 1st May 2015en_US
dc.rights.embargoreasonThesis restricted in accordance with University regulationsen_US


This item appears in the following Collection(s)

Show simple item record