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dc.contributor.authorRaeisaenen, Minna T.
dc.contributor.authorSlater (nee Phillips), Anna G.
dc.contributor.authorChampness, Neil R.
dc.contributor.authorBuck, Manfred
dc.identifier.citationRaeisaenen , M T , Slater (nee Phillips) , A G , Champness , N R & Buck , M 2012 , ' Effects of pore modification on the templating of guest molecules in a 2D honeycomb network ' , Chemical Science , vol. 3 , no. 1 , pp. 84-92 .
dc.identifier.otherPURE: 16504583
dc.identifier.otherPURE UUID: 4a3c756d-118b-4017-ac9c-b4636ee92e0b
dc.identifier.otherWOS: 000297473200010
dc.identifier.otherScopus: 82455166804
dc.identifier.otherORCID: /0000-0003-1225-7607/work/56861201
dc.descriptionThis work was supported by the UK Engineering Physical Sciences Research Council (EPRSC) and the EU.en
dc.description.abstract1,7-Diadamantanethioperylene-3,4:9,10-tetracarboxylic diimide, (Ad-S)(2)-PTCDI, adsorbed on Au (111) from solution was investigated by scanning tunneling microscopy (STM) and X-ray photoelectron spectroscopy (XPS). (Ad-S)(2)-PTCDI forms a well-ordered monolayer whose structure is described by a (2 root 63 x root 19) R19.1 degrees chiral unit cell containing four molecules. Codeposition of (Ad-S)(2)-PTCDI with 1,3,5-triazine-2,4,6-triamine (melamine) yields a honeycomb network whose (7 root 3 x 7 root 3)R30 degrees unit cell is identical to the unsubstituted PTCDI/melamine analogue. The effect of the adamantyl thioether moieties on the adsorption of guest molecules is investigated using adamantane thiol and C-60. While the thioether units do not affect the packing of adamantane thiol molecules a pronounced influence is seen in the case of fullerene. Pore modification involving different combinations of enantiomers of (Ad-S)(2)-PTCDI give rise to distinctly different arrangements of C-60 molecules. The diversity of patterns is further increased by the presence of unsubstituted PTCDI molecules.
dc.relation.ispartofChemical Scienceen
dc.rightsThis is the accepted version of this article. The published version is available in Chemical Science, (c) The Royal Society of Chemistryen
dc.subjectSelf-assembled monolayersen
dc.subject2-dimensional supramolecular networken
dc.subjectLiquid-solid interfaceen
dc.subjectAU(111) surfaceen
dc.subjectQD Chemistryen
dc.titleEffects of pore modification on the templating of guest molecules in a 2D honeycomb networken
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.description.statusPeer revieweden

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