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Effects of pore modification on the templating of guest molecules in a 2D honeycomb network
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dc.contributor.author | Raeisaenen, Minna T. | |
dc.contributor.author | Slater (nee Phillips), Anna G. | |
dc.contributor.author | Champness, Neil R. | |
dc.contributor.author | Buck, Manfred | |
dc.date.accessioned | 2012-09-13T00:20:24Z | |
dc.date.available | 2012-09-13T00:20:24Z | |
dc.date.issued | 2012 | |
dc.identifier.citation | Raeisaenen , M T , Slater (nee Phillips) , A G , Champness , N R & Buck , M 2012 , ' Effects of pore modification on the templating of guest molecules in a 2D honeycomb network ' , Chemical Science , vol. 3 , no. 1 , pp. 84-92 . https://doi.org/10.1039/c1sc00543j | en |
dc.identifier.issn | 2041-6520 | |
dc.identifier.other | PURE: 16504583 | |
dc.identifier.other | PURE UUID: 4a3c756d-118b-4017-ac9c-b4636ee92e0b | |
dc.identifier.other | WOS: 000297473200010 | |
dc.identifier.other | Scopus: 82455166804 | |
dc.identifier.other | ORCID: /0000-0003-1225-7607/work/56861201 | |
dc.identifier.uri | https://hdl.handle.net/10023/3073 | |
dc.description | This work was supported by the UK Engineering Physical Sciences Research Council (EPRSC) and the EU. | en |
dc.description.abstract | 1,7-Diadamantanethioperylene-3,4:9,10-tetracarboxylic diimide, (Ad-S)(2)-PTCDI, adsorbed on Au (111) from solution was investigated by scanning tunneling microscopy (STM) and X-ray photoelectron spectroscopy (XPS). (Ad-S)(2)-PTCDI forms a well-ordered monolayer whose structure is described by a (2 root 63 x root 19) R19.1 degrees chiral unit cell containing four molecules. Codeposition of (Ad-S)(2)-PTCDI with 1,3,5-triazine-2,4,6-triamine (melamine) yields a honeycomb network whose (7 root 3 x 7 root 3)R30 degrees unit cell is identical to the unsubstituted PTCDI/melamine analogue. The effect of the adamantyl thioether moieties on the adsorption of guest molecules is investigated using adamantane thiol and C-60. While the thioether units do not affect the packing of adamantane thiol molecules a pronounced influence is seen in the case of fullerene. Pore modification involving different combinations of enantiomers of (Ad-S)(2)-PTCDI give rise to distinctly different arrangements of C-60 molecules. The diversity of patterns is further increased by the presence of unsubstituted PTCDI molecules. | |
dc.format.extent | 9 | |
dc.language.iso | eng | |
dc.relation.ispartof | Chemical Science | en |
dc.rights | This is the accepted version of this article. The published version is available in Chemical Science, (c) The Royal Society of Chemistry | en |
dc.subject | Self-assembled monolayers | en |
dc.subject | 2-dimensional supramolecular network | en |
dc.subject | Liquid-solid interface | en |
dc.subject | Organic-molecules | en |
dc.subject | AU(111) surface | en |
dc.subject | C-60 | en |
dc.subject | Organization | en |
dc.subject | Fullerenes | en |
dc.subject | Adsorption | en |
dc.subject | Porphyrin | en |
dc.subject | QD Chemistry | en |
dc.subject.lcc | QD | en |
dc.title | Effects of pore modification on the templating of guest molecules in a 2D honeycomb network | en |
dc.type | Journal article | en |
dc.contributor.sponsor | European Commission | en |
dc.contributor.sponsor | EPSRC | en |
dc.description.version | Postprint | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | https://doi.org/10.1039/c1sc00543j | |
dc.description.status | Peer reviewed | en |
dc.date.embargoedUntil | 2012-09-13 | |
dc.identifier.grantnumber | CONTRACT NO: 032109 | en |
dc.identifier.grantnumber | EP/D048761/1 | en |
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