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Dichloro-μ2,μ2-naphthalene-1,8-diyl-bis(N,N,N’,N’-tetrameth- 2 ylethylenediamino)tetracopper(I)
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dc.contributor.author | Ray, Matthew James | |
dc.contributor.author | Saviantoni, Maria L | |
dc.contributor.author | Slawin, Alexandra Martha Zoya | |
dc.contributor.author | Cordes, David Bradford | |
dc.contributor.author | Kilian, Petr | |
dc.date.accessioned | 2024-06-06T08:30:06Z | |
dc.date.available | 2024-06-06T08:30:06Z | |
dc.date.issued | 2024-06-05 | |
dc.identifier | 302521867 | |
dc.identifier | b65d4c75-4661-44f6-bf07-446aecd07ee1 | |
dc.identifier.citation | Ray , M J , Saviantoni , M L , Slawin , A M Z , Cordes , D B & Kilian , P 2024 , ' Dichloro-μ2,μ2-naphthalene-1,8-diyl-bis(N,N,N’,N’-tetrameth- 2 ylethylenediamino)tetracopper(I) ' , Molbank , vol. 2024 , no. 2 , M1832 . https://doi.org/10.3390/M1832 | en |
dc.identifier.issn | 1422-8599 | |
dc.identifier.other | ORCID: /0000-0001-6379-3026/work/161228343 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/161228685 | |
dc.identifier.other | ORCID: /0000-0002-5366-9168/work/161228792 | |
dc.identifier.uri | https://hdl.handle.net/10023/29999 | |
dc.description.abstract | A highly reactive dicuprate/CuCl aggregate, Nap(Cu4Cl2)(TMEDA)2 (2, Nap = naphthalene-1,8-diyl, TMEDA = tetramethylethylenediamine), was synthesized by the reaction of 1,8-dilithionaphthalene(TMEDA)2 with four equivalents of CuCl. The X-ray crystal structure of this complex shows that the four copper atoms form a bent parallelogram-shaped core, with terminally bonded chlorine atoms. The naphthalene ring is bonded through carbons in the 1 and 8 positions (peri-positions), each bridging two copper atoms. | |
dc.format.extent | 7 | |
dc.format.extent | 2205574 | |
dc.language.iso | eng | |
dc.relation.ispartof | Molbank | en |
dc.subject | Synthesis | en |
dc.subject | Peri-substitution | en |
dc.subject | Copper organometallic complex | en |
dc.subject | QD Chemistry | en |
dc.subject | DAS | en |
dc.subject.lcc | QD | en |
dc.title | Dichloro-μ2,μ2-naphthalene-1,8-diyl-bis(N,N,N’,N’-tetrameth- 2 ylethylenediamino)tetracopper(I) | en |
dc.type | Journal article | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | https://doi.org/10.3390/M1832 | |
dc.description.status | Peer reviewed | en |
dc.identifier.url | https://www.mdpi.com/1422-8599/2024/2/M1832 | en |
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