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Direct chemoselective reduction of plant oils using silane catalysed by Rh(iii) complexes at ambient temperature
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dc.contributor.author | P.-Pascual, U. | |
dc.contributor.author | Bustos, I. | |
dc.contributor.author | Freixa, Z. | |
dc.contributor.author | Kumar, Amit | |
dc.contributor.author | Huertos, M. | |
dc.date.accessioned | 2024-03-18T09:30:06Z | |
dc.date.available | 2024-03-18T09:30:06Z | |
dc.date.issued | 2024-02-21 | |
dc.identifier | 300271015 | |
dc.identifier | db59c643-4796-4b71-b9cb-b2e0a21446fb | |
dc.identifier | 85187571978 | |
dc.identifier.citation | P.-Pascual , U , Bustos , I , Freixa , Z , Kumar , A & Huertos , M 2024 , ' Direct chemoselective reduction of plant oils using silane catalysed by Rh(iii) complexes at ambient temperature ' , RSC Sustainability , vol. Advance Article . https://doi.org/10.1039/D3SU00481C | en |
dc.identifier.issn | 2753-8125 | |
dc.identifier.other | ORCID: /0000-0002-8175-8221/work/155626495 | |
dc.identifier.uri | https://hdl.handle.net/10023/29516 | |
dc.description | This publication is part of the projects PID2019-111281GB-I00 funded by MCIN/AEI/10.13039/501100011033 and IT1741-22 and IT1553-22 funded by Gobierno Vasco. The authors thank SGiker for support. Universidad del País Vasco (UPV/EHU) (U. P.) and IKERBASQUE (M. H. and Z. F.) are acknowledged for personnel funding. A. K. acknowledges a UKRI Future Leaders Fellowship for funding (MR/W007460/1). | en |
dc.description.abstract | We report here a rare example of direct and chemoselective catalytic reduction of various plant oils to unsaturated fatty alcohols and glycerol. The selective reduction process is achieved using 0.5 mol% of a rhodium complex and diphenylsilane at room temperature without using any solvent producing a mixture of unsaturated fatty alcohols in yields >90%. We also observed that the selectivity of the reduction process (C[double bond, length as m-dash]C vs. ester) depends on the nature of silane. | |
dc.format.extent | 6 | |
dc.format.extent | 624159 | |
dc.language.iso | eng | |
dc.relation.ispartof | RSC Sustainability | en |
dc.subject | DAS | en |
dc.title | Direct chemoselective reduction of plant oils using silane catalysed by Rh(iii) complexes at ambient temperature | en |
dc.type | Journal article | en |
dc.contributor.sponsor | Medical Research Council | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.identifier.doi | 10.1039/D3SU00481C | |
dc.description.status | Peer reviewed | en |
dc.identifier.grantnumber | MR/W007460/1 | en |
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