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Synthesis and butyllithium-induced cyclisation of 2-benzyloxyphenylphosphonamidates giving 2,3-dihydrobenzo[d][1,3]oxaphospholes
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dc.contributor.author | Aitken, R Alan | |
dc.contributor.author | Ait Moulay, Khadija | |
dc.contributor.author | Cordes, David Bradford | |
dc.contributor.author | Inwood, Ryan | |
dc.contributor.author | Jamieson, Fraser G. | |
dc.contributor.author | Nelson, Alexander J. B. | |
dc.contributor.author | McKay, Aidan | |
dc.date.accessioned | 2024-02-01T11:30:01Z | |
dc.date.available | 2024-02-01T11:30:01Z | |
dc.date.issued | 2024-02-01 | |
dc.identifier | 298265914 | |
dc.identifier | ac406fae-74dc-4d27-b9cc-c6babbd8ca55 | |
dc.identifier | 85188901750 | |
dc.identifier.citation | Aitken , R A , Ait Moulay , K , Cordes , D B , Inwood , R , Jamieson , F G , Nelson , A J B & McKay , A 2024 , ' Synthesis and butyllithium-induced cyclisation of 2-benzyloxyphenylphosphonamidates giving 2,3-dihydrobenzo[ d ][1,3]oxaphospholes ' , Organics , vol. 5 , no. 1 , pp. 12-31 . https://doi.org/10.3390/org5010002 | en |
dc.identifier.issn | 2673-401X | |
dc.identifier.other | ORCID: /0000-0001-6959-5311/work/152318290 | |
dc.identifier.other | ORCID: /0000-0002-5366-9168/work/152318432 | |
dc.identifier.uri | https://hdl.handle.net/10023/29127 | |
dc.description | Authors thank EPSRC (UK) and CRITICAT Centre for Doctoral Training for a studentship to R.A.I. (Grant EP/L016419/1). | en |
dc.description.abstract | A series of fourteen O-ethyl-N-butylphenylphosphonamidates with benzyl ether substituents at the ortho position have been prepared and fully characterised. Upon treatment with n-butyllithium in THF at RT, these undergo cyclisation in eight cases to give the novel 2,3-dihydrobenzo[d][1,3]oxaphospholes in moderate to low yield as a single diastereomer for which the relative configuration has been determined by X-ray diffraction in one case. | |
dc.format.extent | 20 | |
dc.format.extent | 1053309 | |
dc.language.iso | eng | |
dc.relation.ispartof | Organics | en |
dc.subject | 1,3-dihydrobenzo[d][1,3]oxaphosphole | en |
dc.subject | 1,3-benzoxaphosphole | en |
dc.subject | Phosphonamidate | en |
dc.subject | X-ray structure | en |
dc.subject | Hydrogen bonding | en |
dc.subject | QD Chemistry | en |
dc.subject | DAS | en |
dc.subject.lcc | QD | en |
dc.title | Synthesis and butyllithium-induced cyclisation of 2-benzyloxyphenylphosphonamidates giving 2,3-dihydrobenzo[d][1,3]oxaphospholes | en |
dc.type | Journal article | en |
dc.contributor.sponsor | EPSRC | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.identifier.doi | https://doi.org/10.3390/org5010002 | |
dc.description.status | Peer reviewed | en |
dc.identifier.url | https://www.mdpi.com/2673-401X/5/1/2 | en |
dc.identifier.grantnumber | EP/L016419/1 | en |
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