Show simple item record

Files in this item

Thumbnail
Name:
Rice_2023_CGD_ADOR_CCBY.pdf
Size:
2.952Mb
Format:
PDF
View/Open

Investigations of the ADOR process using solid-state NMR spectroscopy

Item metadata

dc.contributor.authorRice, Cameron M.
dc.contributor.authorDovernor, Olivia J.
dc.contributor.authorMorris, Russell E.
dc.contributor.authorAshbrook, Sharon E.
dc.date.accessioned2023-11-17T10:30:15Z
dc.date.available2023-11-17T10:30:15Z
dc.date.issued2023-11-15
dc.identifier295575485
dc.identifiera8b6fe68-5c23-4e59-ba52-ee5872e89cf8
dc.identifier85179172735
dc.identifier.citationRice , C M , Dovernor , O J , Morris , R E & Ashbrook , S E 2023 , ' Investigations of the ADOR process using solid-state NMR spectroscopy ' , Crystal Growth & Design , vol. Articles ASAP . https://doi.org/10.1021/acs.cgd.3c01037en
dc.identifier.issn1528-7483
dc.identifier.otherORCID: /0000-0002-4538-6782/work/146963945
dc.identifier.otherORCID: /0000-0001-7809-0315/work/146964465
dc.identifier.urihttps://hdl.handle.net/10023/28724
dc.descriptionThe authors are grateful for financial assistance from the European Research Council under advanced grant ADOR AdG 787073 and the EPSRC for a studentship (EP/N509759/1). The UK High-Field Solid-State NMR Facility used in this research was funded by EPSRC and BBSRC (EP/T015063/1), as well as the University of Warwick, Birmingham Science City Advanced Materials Projects 1 and 2 supported by Advantage West Midlands (AWM) and the European Regional Development Fund (ERDF), as well as, for the 1 GHz instrument, EP/R029946/1.en
dc.description.abstractThe assembly–disassembly–organization–reassembly (ADOR) process for the transformation of zeolite UTL using water has been studied by using 29Si and 17O solid-state NMR spectroscopy. The results show that the intermediate materials that are formed during the reaction are extremely dynamic and that the process involves both irreversible changes in structure that define the overall pathway and reversible lability of the Si–O–Si linkages that have no effect on the overall structure. The combination of processes occurring during the ADOR reaction means that the mechanism is considerably more complex than initially proposed.
dc.format.extent10
dc.format.extent3096092
dc.language.isoeng
dc.relation.ispartofCrystal Growth & Designen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleInvestigations of the ADOR process using solid-state NMR spectroscopyen
dc.typeJournal articleen
dc.contributor.sponsorEuropean Research Councilen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.identifier.doi10.1021/acs.cgd.3c01037
dc.description.statusPeer revieweden
dc.identifier.grantnumber787073en


This item appears in the following Collection(s)

Show simple item record

Items in the St Andrews Research Repository are protected by copyright, with all rights reserved, unless otherwise indicated.