Synthesis of FeAPO-34 molecular sieve under ionothermal condition
Abstract
FeAPO-34 with chabazite (CHA) topology structure was successfully synthesized under ionothermal conditions using 1-ethyl-3-methylimidazoliumchloride (EMIMCl) ionic liquid in the presence of ethylenediamine (EDA). The material was characterised using powder Xray Diffraction (XRD), thermogravimetric analysis (TGA), elemental analyses and solid-state NMR spectroscopy. Incorporation of iron within the covalent framework of the material was confirmed by the presence of broad signals between 1000 and 14000 ppm in the 31P NMR spectrum, corresponding to P(OFe)x(OAl)4–x species.
Citation
Musa , M , Dawson , D M , Morris , R E & Ashbrook , S E 2022 , ' Synthesis of FeAPO-34 molecular sieve under ionothermal condition ' , Inorganic Chemistry , vol. 61 , no. 42 , pp. 16685-16692 . https://doi.org/10.1021/acs.inorgchem.2c02352
Publication
Inorganic Chemistry
Status
Peer reviewed
ISSN
0020-1669Type
Journal article
Rights
Copyright © 2022 American Chemical Society. This work has been made available online in accordance with publisher policies or with permission. Permission for further reuse of this content should be sought from the publisher or the rights holder. This is the author created accepted manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1021/acs.inorgchem.2c02352
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