Pressure and guest-mediated pore shape modification in a small pore MOF to 1200 bar

McMonagle, Charles J.; Turner, Gemma F.; Jones, Isabelle; Allan, David R.; Warren, Mark R.; Kamenev, Konstantin V.; Parsons, Simon; Wright, Paul A.; Moggach, Stephen A.

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dc.contributor.author	McMonagle, Charles J.
dc.contributor.author	Turner, Gemma F.
dc.contributor.author	Jones, Isabelle
dc.contributor.author	Allan, David R.
dc.contributor.author	Warren, Mark R.
dc.contributor.author	Kamenev, Konstantin V.
dc.contributor.author	Parsons, Simon
dc.contributor.author	Wright, Paul A.
dc.contributor.author	Moggach, Stephen A.
dc.date.accessioned	2023-09-15T23:36:43Z
dc.date.available	2023-09-15T23:36:43Z
dc.date.issued	2022-10-21
dc.identifier.citation	McMonagle , C J , Turner , G F , Jones , I , Allan , D R , Warren , M R , Kamenev , K V , Parsons , S , Wright , P A & Moggach , S A 2022 , ' Pressure and guest-mediated pore shape modification in a small pore MOF to 1200 bar ' , Chemical Communications , vol. 58 , no. 82 , pp. 11465–11598 . https://doi.org/10.1039/d2cc04649k	en
dc.identifier.issn	1359-7345
dc.identifier.other	PURE: 281863861
dc.identifier.other	PURE UUID: 83b54092-6177-453e-8bc4-dc99004a5132
dc.identifier.other	Jisc: 635065
dc.identifier.other	Scopus: 85139804124
dc.identifier.other	WOS: 000856041100001
dc.identifier.other	ORCID: /0000-0002-4243-9957/work/121754280
dc.identifier.uri	http://hdl.handle.net/10023/28406
dc.description	The authors acknowledge Diamond Light Source, Rutherford Appleton Laboratories, for beamtime on Station I19 and the staff on beamline I19 for assistance, and for providing funding for a PhD studentship to CJM. GFT acknowledges the Australian Government for the provision of an RTP scholarship. SAM thanks the Australian Research Council (ARC) for a Future Fellowship (FT200100243).	en
dc.description.abstract	Guest-mediated pore-shape modification of the metal–organic framework, Sc2BDC3 upon adsorption of n-pentane and isopentane is examined from 50–1200 bar. Rotation of the BDC linker responsible for the change in pore shape occurs at much lower pressures than previously reported, with distinct adsorption behaviour observed between pentane isomers.
dc.format.extent	4
dc.language.iso	eng
dc.relation.ispartof	Chemical Communications	en
dc.rights	Copyright © 2022 The Author(s). This work has been made available online in accordance with publisher policies or with permission. Permission for further reuse of this content should be sought from the publisher or the rights holder. This is the author created accepted manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1039/D2CC04649K	en
dc.subject	QD Chemistry	en
dc.subject	DAS	en
dc.subject	AC	en
dc.subject.lcc	QD	en
dc.title	Pressure and guest-mediated pore shape modification in a small pore MOF to 1200 bar	en
dc.type	Journal article	en
dc.description.version	Postprint	en
dc.contributor.institution	University of St Andrews. EaSTCHEM	en
dc.contributor.institution	University of St Andrews. School of Chemistry	en
dc.identifier.doi	https://doi.org/10.1039/d2cc04649k
dc.description.status	Peer reviewed	en
dc.date.embargoedUntil	2023-09-16

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