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Pressure and guest-mediated pore shape modification in a small pore MOF to 1200 bar

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dc.contributor.authorMcMonagle, Charles J.
dc.contributor.authorTurner, Gemma F.
dc.contributor.authorJones, Isabelle
dc.contributor.authorAllan, David R.
dc.contributor.authorWarren, Mark R.
dc.contributor.authorKamenev, Konstantin V.
dc.contributor.authorParsons, Simon
dc.contributor.authorWright, Paul A.
dc.contributor.authorMoggach, Stephen A.
dc.date.accessioned2023-09-15T23:36:43Z
dc.date.available2023-09-15T23:36:43Z
dc.date.issued2022-10-21
dc.identifier281863861
dc.identifier83b54092-6177-453e-8bc4-dc99004a5132
dc.identifier85139804124
dc.identifier000856041100001
dc.identifier.citationMcMonagle , C J , Turner , G F , Jones , I , Allan , D R , Warren , M R , Kamenev , K V , Parsons , S , Wright , P A & Moggach , S A 2022 , ' Pressure and guest-mediated pore shape modification in a small pore MOF to 1200 bar ' , Chemical Communications , vol. 58 , no. 82 , pp. 11465–11598 . https://doi.org/10.1039/d2cc04649ken
dc.identifier.issn1359-7345
dc.identifier.otherJisc: 635065
dc.identifier.otherORCID: /0000-0002-4243-9957/work/121754280
dc.identifier.urihttps://hdl.handle.net/10023/28406
dc.descriptionThe authors acknowledge Diamond Light Source, Rutherford Appleton Laboratories, for beamtime on Station I19 and the staff on beamline I19 for assistance, and for providing funding for a PhD studentship to CJM. GFT acknowledges the Australian Government for the provision of an RTP scholarship. SAM thanks the Australian Research Council (ARC) for a Future Fellowship (FT200100243).en
dc.description.abstractGuest-mediated pore-shape modification of the metal–organic framework, Sc2BDC3 upon adsorption of n-pentane and isopentane is examined from 50–1200 bar. Rotation of the BDC linker responsible for the change in pore shape occurs at much lower pressures than previously reported, with distinct adsorption behaviour observed between pentane isomers.
dc.format.extent4
dc.format.extent619467
dc.language.isoeng
dc.relation.ispartofChemical Communicationsen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subjectACen
dc.subject.lccQDen
dc.titlePressure and guest-mediated pore shape modification in a small pore MOF to 1200 baren
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.identifier.doihttps://doi.org/10.1039/d2cc04649k
dc.description.statusPeer revieweden
dc.date.embargoedUntil2023-09-16


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