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Room-temperature multiple phosphorescence from functionalized corannulenes : temperature sensing and afterglow organic light-emitting diode
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dc.contributor.author | Si, Changfeng | |
dc.contributor.author | Wang, Tao | |
dc.contributor.author | Gupta, Abhishek Kumar | |
dc.contributor.author | Cordes, David Bradford | |
dc.contributor.author | Slawin, Alexandra Martha Zoya | |
dc.contributor.author | Siegel, Jay S. | |
dc.contributor.author | Zysman-Colman, Eli | |
dc.date.accessioned | 2023-09-15T10:30:03Z | |
dc.date.available | 2023-09-15T10:30:03Z | |
dc.date.issued | 2023-10-23 | |
dc.identifier | 293650472 | |
dc.identifier | fe764d1e-4960-49ea-acbb-bb227138e3b2 | |
dc.identifier | 85171298744 | |
dc.identifier.citation | Si , C , Wang , T , Gupta , A K , Cordes , D B , Slawin , A M Z , Siegel , J S & Zysman-Colman , E 2023 , ' Room-temperature multiple phosphorescence from functionalized corannulenes : temperature sensing and afterglow organic light-emitting diode ' , Angewandte Chemie International Edition , vol. 62 , no. 43 , e202309718 . https://doi.org/10.1002/anie.202309718 | en |
dc.identifier.issn | 1433-7851 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/142499219 | |
dc.identifier.other | ORCID: /0000-0002-5366-9168/work/142499307 | |
dc.identifier.other | ORCID: /0000-0001-7183-6022/work/142499562 | |
dc.identifier.uri | https://hdl.handle.net/10023/28391 | |
dc.description | C. Si thanks the China Scholarship Council (201806890001).This project has received funding from the European Union’s Horizon 2020 research and innovation programme under the Marie Skłodowska-Curie grant agreement No. 897098 (AIE-RTP-PLED). T.W. acknowledges support from the Marie Skłodowska-Curie Individual Fellowship. We thank the EPSRC (EP/R035164/1) for financial support. | en |
dc.description.abstract | Corannulene-derived materials have been extensively explored in energy storage and solar cells, but, however, are rarely documented as emitters in light-emitting sensors and organic light-emitting diodes (OLEDs), due to low exciton utilization. Here, we report a family of multi-donor and acceptor (multi-D-A) motifs, TCzPhCor, TDMACPhCor, and TPXZPhCor, using corannulene as the acceptor and carbazole (Cz), 9,10-dihydro-9,10-dimethylacridine (DMAC), and phenoxazine (PXZ) as the donor, respectively. By decorating corannulene with different donors, multiple phosphorescence is realized. Theoretical and photophysical investigations reveal that TCzPhCor shows room-temperature phosphorescence (RTP) from the lowest-lying T1; however, for TDMACPhCor, dual RTP originating from a higher-lying T1 (T1H) and a lower-lying T1 (T1L) can be observed, while for TPXZPhCor, T1H-dominated RTP occurs resulting from a stabilized high-energy T1 geometry. Benefiting from the high-temperature sensitivity of TPXZPhCor, high color-resolution temperature sensing is achieved. Besides, due to degenerate S1 and T1H states of TPXZPhCor, the first corannulene-based solution-processed afterglow organic light-emitting diodes (OLEDs) is investigated. The afterglow OLED with TPXZPhCor shows a maximum external quantum efficiency (EQEmax) and a luminance (Lmax) of 3.3% and 5167 cd m-2, respectively, which is one of the most efficient afterglow RTP OLEDs reported to date. | |
dc.format.extent | 13 | |
dc.format.extent | 14593592 | |
dc.language.iso | eng | |
dc.relation.ispartof | Angewandte Chemie International Edition | en |
dc.subject | Afterglow organic light-emitting diode | en |
dc.subject | Corannulene | en |
dc.subject | Multiple phosphorescence | en |
dc.subject | Room-temperature phosphorescence | en |
dc.subject | Temperature sensing | en |
dc.subject | QD Chemistry | en |
dc.subject | DAS | en |
dc.subject.lcc | QD | en |
dc.title | Room-temperature multiple phosphorescence from functionalized corannulenes : temperature sensing and afterglow organic light-emitting diode | en |
dc.type | Journal article | en |
dc.contributor.sponsor | European Commission | en |
dc.contributor.sponsor | EPSRC | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. Institute of Behavioural and Neural Sciences | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.contributor.institution | University of St Andrews. Centre for Energy Ethics | en |
dc.identifier.doi | 10.1002/anie.202309718 | |
dc.description.status | Peer reviewed | en |
dc.identifier.grantnumber | 879098 | en |
dc.identifier.grantnumber | EP/R035164/1 | en |
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