Show simple item record

Files in this item

Thumbnail
Name:
Bru_2022_CEJ_versatile_palladium_AAM.pdf
Size:
1.677Mb
Format:
PDF
View/Open

A versatile palladium synthon: [Pd(NHC)(PhC≡CPh)]

Item metadata

dc.contributor.authorBru, Francis
dc.contributor.authorLesieur, Mathieu
dc.contributor.authorPoater, Albert
dc.contributor.authorSlawin, Alexandra
dc.contributor.authorCavallo, Luigi
dc.contributor.authorCazin, Catherine
dc.date.accessioned2023-09-04T23:36:13Z
dc.date.available2023-09-04T23:36:13Z
dc.date.issued2022-10-05
dc.identifier281335201
dc.identifier2eaf8991-072f-4515-b2fc-7ed3049e9f26
dc.identifier000863947300001
dc.identifier85139408456
dc.identifier.citationBru , F , Lesieur , M , Poater , A , Slawin , A , Cavallo , L & Cazin , C 2022 , ' A versatile palladium synthon: [Pd(NHC)(PhC≡CPh)] ' , Chemistry - A European Journal , vol. Early View , e202201917 . https://doi.org/10.1002/chem.202201917en
dc.identifier.issn0947-6539
dc.identifier.otherJisc: 594380
dc.identifier.otherORCID: /0000-0002-9527-6418/work/121753931
dc.identifier.urihttps://hdl.handle.net/10023/28306
dc.descriptionWe gratefully acknowledge support of this research by the FWO(G054619N) and the UGentBOF. A.P. is a Serra Húnter Fellow and ICREA Academia Prize 2019 and thanks the Spanish Ministerio de Ciencia e Innovación for project PID2021-127423NB-I00. L.C. thanks the King Abdullah University of Science and Technology (KAUST) Supercomputing Laboratory (KSL).en
dc.description.abstractThe synthesis and isolation of [Pd(NHC)(PhC≡CPh)] complexes are reported. These new 14-electron Pd(0)-complexes are key synthons leading to known palladium(0) and palladium(II) species, as well as permitting access to unprecedented mixed NHC-phosphite palladium(0) complexes.This motif permits the facile catalytic hydrosilylation of allenes. DFT calculations have allowed to characterize the relatively weak interaction between the metal and the diphenylacetylene ligand, with a comparison with a series of ligands with more or less coordinating power, bearing varied structural and electronic effects.
dc.format.extent1758549
dc.language.isoeng
dc.relation.ispartofChemistry - A European Journalen
dc.subjectAlkyne ligandsen
dc.subjectCarbene ligandsen
dc.subjectHomogeous catalysisen
dc.subjectHydrosilylationen
dc.subjectPalladiumen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subjectNISen
dc.subject.lccQDen
dc.titleA versatile palladium synthon: [Pd(NHC)(PhC≡CPh)]en
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doi10.1002/chem.202201917
dc.description.statusPeer revieweden
dc.date.embargoedUntil2023-09-05


This item appears in the following Collection(s)

Show simple item record

Items in the St Andrews Research Repository are protected by copyright, with all rights reserved, unless otherwise indicated.