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Brominated B1-polycyclic aromatic hydrocarbons for the synthesis of deep-red to near-infrared delayed fluorescence emitters

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dc.contributor.authorYuan, Kang
dc.contributor.authorGupta, Abhishek Kumar
dc.contributor.authorSi, Changfeng
dc.contributor.authorUzelac, Marina
dc.contributor.authorZysman-Colman, Eli
dc.contributor.authorIngleson, Michael James
dc.date.accessioned2023-07-27T16:30:02Z
dc.date.available2023-07-27T16:30:02Z
dc.date.issued2023-08-11
dc.identifier291257852
dc.identifier5301cb8e-a45c-4312-b28a-6870a436f81b
dc.identifier85167807600
dc.identifier.citationYuan , K , Gupta , A K , Si , C , Uzelac , M , Zysman-Colman , E & Ingleson , M J 2023 , ' Brominated B 1 -polycyclic aromatic hydrocarbons for the synthesis of deep-red to near-infrared delayed fluorescence emitters ' , Organic Letters , vol. 25 , no. 31 , pp. 5880-5884 . https://doi.org/10.1021/acs.orglett.3c02167en
dc.identifier.issn1523-7060
dc.identifier.otherRIS: urn:CAC4A5902645EE4E2B95BDF01900768D
dc.identifier.otherORCID: /0000-0001-7183-6022/work/139555254
dc.identifier.urihttps://hdl.handle.net/10023/28049
dc.descriptionFunding: This project has received funding from the Leverhulme Trust (Grant RPG-2022-032) and the European Research Council (ERC) under the European Union’s Horizon 2020 research and innovation program (Grant Agreement 769599). C.S. thanks the China Scholarship Council (201806890001), and M.I. and E.Z.-C. thank the EPSRC Programme Grant “Boron: Beyond the Reagent” (EP/W007517) for support.en
dc.description.abstractBromo-functionalized B1-polycyclic aromatic hydrocarbons (PAHs) with LUMOs of less than −3.0 eV were synthesized and used in cross-couplings to form donor–acceptor materials. These materials spanned a range of S1 energies, with a number showing thermally activated delayed fluorescence and significant emission in the near-infrared region of the spectrum. These B1-PAHs represent a useful family of acceptors that can be readily synthesized and functionalized.
dc.format.extent5
dc.format.extent2478607
dc.language.isoeng
dc.relation.ispartofOrganic Lettersen
dc.subjectQD Chemistryen
dc.subjectQH301 Biologyen
dc.subjectDASen
dc.subjectACen
dc.subjectMCCen
dc.subject.lccQDen
dc.subject.lccQH301en
dc.titleBrominated B1-polycyclic aromatic hydrocarbons for the synthesis of deep-red to near-infrared delayed fluorescence emittersen
dc.typeJournal articleen
dc.contributor.sponsorThe Leverhulme Trusten
dc.contributor.sponsorUK Research and Innovationen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. Institute of Behavioural and Neural Sciencesen
dc.contributor.institutionUniversity of St Andrews. Centre for Energy Ethicsen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doi10.1021/acs.orglett.3c02167
dc.description.statusPeer revieweden
dc.identifier.grantnumberRPG-2022-032en
dc.identifier.grantnumberEP/W007517/1en


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