Show simple item record

Files in this item

Thumbnail
Name:
Manuscript_accepted.pdf
Size:
943.3Kb
Format:
PDF
View/Open

A molecular aluminium fulleride

Item metadata

dc.contributor.authorLawrence, Samuel
dc.contributor.authorRüffer, Tobias
dc.contributor.authorStasch, Andreas
dc.contributor.authorKretschmer, Robert
dc.date.accessioned2023-07-17T15:30:10Z
dc.date.available2023-07-17T15:30:10Z
dc.date.issued2023-06-28
dc.identifier286935921
dc.identifierb4740067-2c0e-4d52-9d87-f3846cedbf79
dc.identifier85161533430
dc.identifier.citationLawrence , S , Rüffer , T , Stasch , A & Kretschmer , R 2023 , ' A molecular aluminium fulleride ' , Chemical Communications , vol. 59 , no. 51 , pp. 7923-7926 . https://doi.org/10.1039/D3CC01609Aen
dc.identifier.issn1359-7345
dc.identifier.otherORCID: /0000-0002-7407-8287/work/139157332
dc.identifier.urihttps://hdl.handle.net/10023/27975
dc.descriptionFunding: The project was financially supported by the Deutsche Forschungsgemeinschaft (DFG, KR4782/3-1), the EPSRC (PhD studentship for S. R. L.; EP/N509759/1), and the Chemnitz University of Technology.en
dc.description.abstractThe reaction of alumylene [(Dippnacnac)Al] (1) with C60 fashions the first example of a structurally characterised aluminium-fulleride complex, [{(Dippnacnac)Al}3C60] (2), in which the Al centres are covalently bound to significantly elongated 6:6 bonds. Hydrolysis of 2 yields C60H6 and the reaction of 2 with [{Mesnacnac)Mg}2] cleaved the Al fragments by affording the fulleride [{Mesnacnac)Mg}6C60].
dc.format.extent4
dc.format.extent966036
dc.language.isoeng
dc.relation.ispartofChemical Communicationsen
dc.subjectQD Chemistryen
dc.subjectT-NDASen
dc.subjectMCCen
dc.subject.lccQDen
dc.titleA molecular aluminium fullerideen
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.identifier.doi10.1039/D3CC01609A
dc.description.statusPeer revieweden
dc.date.embargoedUntil2023-07-17


This item appears in the following Collection(s)

Show simple item record

Items in the St Andrews Research Repository are protected by copyright, with all rights reserved, unless otherwise indicated.