Files in this item
(Decacarbonyl)(1-isopropyl-2-phenyl-1,2,5,6-tetrahydroacenaphtho [5,6-cd][1,2]diphosphole)ditungsten(0)
Item metadata
dc.contributor.author | Davis, Zachary H. | |
dc.contributor.author | Carpenter-Warren, Cameron L. | |
dc.contributor.author | Taylor, Laurence J. | |
dc.contributor.author | Slawin, Alexandra M. Z. | |
dc.contributor.author | Kilian, Petr | |
dc.contributor.author | Chalmers, Brian A. | |
dc.date.accessioned | 2023-06-20T14:30:07Z | |
dc.date.available | 2023-06-20T14:30:07Z | |
dc.date.issued | 2023-06-16 | |
dc.identifier | 288908608 | |
dc.identifier | d28e3e93-41d5-4184-97e1-d5e6753f2065 | |
dc.identifier | 85163716139 | |
dc.identifier.citation | Davis , Z H , Carpenter-Warren , C L , Taylor , L J , Slawin , A M Z , Kilian , P & Chalmers , B A 2023 , ' (Decacarbonyl)(1-isopropyl-2-phenyl-1,2,5,6-tetrahydroacenaphtho [5,6-cd][1,2]diphosphole)ditungsten(0) ' , Molbank , vol. 2023 , no. 2 , M1671 . https://doi.org/10.3390/M1671 | en |
dc.identifier.issn | 1422-8599 | |
dc.identifier.other | RIS: urn:A615AF8480F5959B469E3784C0A19A9E | |
dc.identifier.other | ORCID: /0000-0002-2999-2272/work/137494599 | |
dc.identifier.other | ORCID: /0000-0001-6379-3026/work/137494753 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/137494896 | |
dc.identifier.uri | https://hdl.handle.net/10023/27802 | |
dc.description.abstract | A binuclear tungsten(0) complex with an asymmetric bridging 1,2-diphosphole ligand was prepared by the photolysis of tungsten hexacarbonyl in the presence of 1-isopropyl-2-phenyl-1,2,5,6-tetrahydroacenaphtho [5,6-cd][1,2]diphosphole. The tungsten complex 1 was characterized by high resolution mass spectrometry, multinuclear NMR spectroscopy (1H, 13C, 31P), and elemental microanalysis. The structure of the trans isomer was resolved by single crystal X-ray diffraction, showing a slight elongation of the P−P bond upon coordination to the W(CO)5 groups. | |
dc.format.extent | 6 | |
dc.format.extent | 1941073 | |
dc.language.iso | eng | |
dc.relation.ispartof | Molbank | en |
dc.subject | X-ray crystallography | en |
dc.subject | NMR spectroscopy | en |
dc.subject | Inert atmosphere synthesis | en |
dc.subject | Phosphorus | en |
dc.subject | Tungsten | en |
dc.subject | Binuclear complex | en |
dc.subject | QD Chemistry | en |
dc.subject | DAS | en |
dc.subject | MCC | en |
dc.subject.lcc | QD | en |
dc.title | (Decacarbonyl)(1-isopropyl-2-phenyl-1,2,5,6-tetrahydroacenaphtho [5,6-cd][1,2]diphosphole)ditungsten(0) | en |
dc.type | Journal article | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | https://doi.org/10.3390/M1671 | |
dc.description.status | Peer reviewed | en |
This item appears in the following Collection(s)
Items in the St Andrews Research Repository are protected by copyright, with all rights reserved, unless otherwise indicated.