Files in this item
Phosphine-stibine and phosphine-stiborane peri-substituted donor-acceptor complexes
Item metadata
dc.contributor.author | Bergsch, Jan U. | |
dc.contributor.author | Slawin, Alexandra Martha Zoya | |
dc.contributor.author | Kilian, Petr | |
dc.contributor.author | Chalmers, Brian Alexander | |
dc.date.accessioned | 2023-05-30T16:30:08Z | |
dc.date.available | 2023-05-30T16:30:08Z | |
dc.date.issued | 2023-05-30 | |
dc.identifier | 286590202 | |
dc.identifier | bf300209-4ec4-4fd3-81ab-5da78fd47dcd | |
dc.identifier | 85163723107 | |
dc.identifier.citation | Bergsch , J U , Slawin , A M Z , Kilian , P & Chalmers , B A 2023 , ' Phosphine-stibine and phosphine-stiborane peri -substituted donor-acceptor complexes ' , Molbank , vol. 2023 , no. 2 , M1653 . https://doi.org/10.3390/M1653 | en |
dc.identifier.issn | 1422-8599 | |
dc.identifier.other | ORCID: /0000-0002-2999-2272/work/136288351 | |
dc.identifier.other | ORCID: /0000-0001-6379-3026/work/136288468 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/136288706 | |
dc.identifier.uri | https://hdl.handle.net/10023/27700 | |
dc.description.abstract | Two novel Sb(III) and Sb(V) peri-substituted acenaphthene phosphorus−antimony compounds were prepared. The Sb(III) compound, 1, was prepared via reacting the organolithium precursor with dichloro(p-tolyl)Stibine, and 2 was prepared by the chlorination of 1. Both 1 and 2 were characterized by multinuclear (1H, 13C and 31P) NMR spectroscopy, and their molecular structures resolved by single-crystal X-ray diffraction. Both compounds show a dative P−Sb interaction with the antimony being the acceptor group in both cases owing to its Lewis acidity. | |
dc.format.extent | 9 | |
dc.format.extent | 1570885 | |
dc.language.iso | eng | |
dc.relation.ispartof | Molbank | en |
dc.subject | X-ray crystallography | en |
dc.subject | Donor-acceptor | en |
dc.subject | p-block chemistry | en |
dc.subject | NMR spectroscopy | en |
dc.subject | Inert atmosphere synthesis | en |
dc.subject | Phosphorous | en |
dc.subject | Antimony | en |
dc.subject | QD Chemistry | en |
dc.subject | QH301 Biology | en |
dc.subject | DAS | en |
dc.subject | MCC | en |
dc.subject.lcc | QD | en |
dc.subject.lcc | QH301 | en |
dc.title | Phosphine-stibine and phosphine-stiborane peri-substituted donor-acceptor complexes | en |
dc.type | Journal article | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.identifier.doi | 10.3390/M1653 | |
dc.description.status | Peer reviewed | en |
dc.identifier.url | https://www.mdpi.com/1422-8599/2023/2/M1653 | en |
This item appears in the following Collection(s)
Items in the St Andrews Research Repository are protected by copyright, with all rights reserved, unless otherwise indicated.