Solid state structure and hydrogen bonding of some cyclic NH carboximides
Date
15/01/2023Metadata
Show full item recordAbstract
Thirteen new crystal structures of cyclic NH carboximides have been determined and are compared with respect to the mode of intermolecular hydrogen bonding observed in the crystal. The structures include a new cyclobutane-fused succinimide, seven new simple bi- and tricyclic succinimides derived from Diels-Alder reactions of maleimide, three methylated glutarimides, a morpholinedione and adipimide, the first seven-membered ring NH carboximide to be structurally characterised. Overall seven of the compounds adopt a ribbon structure, five show centro-symmetric dimers, and one has bonding between NH and a remote bridging ether oxygen. Halogen bonding was also detected in one case.
Citation
Aitken , R A , Nelson , A J B , Slawin , A M Z & Sonecha , D K 2023 , ' Solid state structure and hydrogen bonding of some cyclic NH carboximides ' , Crystals , vol. 13 , no. 1 , 150 . https://doi.org/10.3390/cryst13010150
Publication
Crystals
Status
Peer reviewed
ISSN
2073-4352Type
Journal article
Rights
Copyright: © 2023 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0).
Collections
Items in the St Andrews Research Repository are protected by copyright, with all rights reserved, unless otherwise indicated.