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1,3,3,3',3'-Pentaisopropyl-1,3,3',6,6',7,7'-heptahydro-1λ5-1,1'-spirobi[acenaphtho[5,6-cd][1,2,6]oxadiphosphinine]-3,3'-diium triiodide

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dc.contributor.authorPicthall, Daniel
dc.contributor.authorRay, Matthew
dc.contributor.authorSlawin, Alexandra Martha Zoya
dc.contributor.authorKilian, Petr
dc.date.accessioned2022-12-08T15:30:12Z
dc.date.available2022-12-08T15:30:12Z
dc.date.issued2022-12-08
dc.identifier.citationPicthall , D , Ray , M , Slawin , A M Z & Kilian , P 2022 , ' 1,3,3,3',3'-Pentaisopropyl-1,3,3',6,6',7,7'-heptahydro-1λ5-1,1'-spirobi[acenaphtho[5,6-cd][1,2,6]oxadiphosphinine]-3,3'-diium triiodide ' , Molbank , vol. 2022 , no. 4 , M1523 . https://doi.org/10.3390/M1523en
dc.identifier.issn1422-8599
dc.identifier.otherPURE: 282460130
dc.identifier.otherPURE UUID: a1a54386-56be-41a2-bb7c-da2886ad78a2
dc.identifier.otherORCID: /0000-0001-6379-3026/work/124489875
dc.identifier.otherORCID: /0000-0002-9527-6418/work/124489956
dc.identifier.otherScopus: 85144673449
dc.identifier.otherWOS: 000902683100001
dc.identifier.urihttps://hdl.handle.net/10023/26562
dc.descriptionFunding: This research was funded by School of Chemistry, University of St Andrews.en
dc.description.abstractReaction of bis(peri-substituted) triphosphine iPr(AcenapPiPr2)2 (Acenap = acenaphthene-5,6-diyl) with iodine, followed by hydrolysis, afforded ionic species with [iPr(AcenapP(O)iPr2)2] dication, containing P-O-P-O-P motif, balanced by triiodide anions. The new species were fully characterized including single crystal X-ray diffraction. Formation of the unusual double bridged motif is likely a result of crowding in the peri-region.
dc.format.extent5
dc.language.isoeng
dc.relation.ispartofMolbanken
dc.rightsCopyright: © 2022 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https:// creativecommons.org/licenses/by/ 4.0/).en
dc.subjectPhosphineen
dc.subjectHalophosphonium halideen
dc.subjectSynthesisen
dc.subjectPeri-substitutionen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subjectMCCen
dc.subject.lccQDen
dc.title1,3,3,3',3'-Pentaisopropyl-1,3,3',6,6',7,7'-heptahydro-1λ5-1,1'-spirobi[acenaphtho[5,6-cd][1,2,6]oxadiphosphinine]-3,3'-diium triiodideen
dc.typeJournal articleen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doihttps://doi.org/10.3390/M1523
dc.description.statusPeer revieweden


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