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Dual NHC/photoredox catalytic synthesis of 1,4-diketones using an MR-TADF photocatalyst (DiKTa)

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dc.contributor.authorPrentice, Callum
dc.contributor.authorMorrison, James
dc.contributor.authorZysman-Colman, Eli
dc.contributor.authorSmith, Andrew D.
dc.date.accessioned2022-12-02T16:30:13Z
dc.date.available2022-12-02T16:30:13Z
dc.date.issued2022-12-21
dc.identifier282081576
dc.identifier4bb4003e-b7bc-4cb1-b7cf-427d5878a36b
dc.identifier85142786179
dc.identifier.citationPrentice , C , Morrison , J , Zysman-Colman , E & Smith , A D 2022 , ' Dual NHC/photoredox catalytic synthesis of 1,4-diketones using an MR-TADF photocatalyst (DiKTa) ' , Chemical Communications , vol. 58 , no. 98 , pp. 13624-13627 . https://doi.org/10.26434/chemrxiv-2022-20dvn , https://doi.org/10.1039/D2CC05705Ken
dc.identifier.issn1359-7345
dc.identifier.otherORCID: /0000-0002-2104-7313/work/122720336
dc.identifier.otherORCID: /0000-0001-7183-6022/work/122720451
dc.identifier.urihttps://hdl.handle.net/10023/26533
dc.descriptionFunding: The authors thank AstraZeneca and the University of St Andrews for funding (Case studentship to C.P.).en
dc.description.abstractThe use of the recently reported organic multi-resonant thermally activated delayed fluorescence (MR-TADF) photocatalyst DiKTa allows for the modular synthesis of 1,4-diketones under mild and metal-free conditions. The reaction proceeds via a three-component relay process in the presence of an N-heterocyclic carbene (NHC) organocatalyst.
dc.format.extent4
dc.format.extent1593586
dc.language.isoeng
dc.relation.ispartofChemical Communicationsen
dc.subjectQD Chemistryen
dc.subjectNDASen
dc.subjectMCCen
dc.subject.lccQDen
dc.titleDual NHC/photoredox catalytic synthesis of 1,4-diketones using an MR-TADF photocatalyst (DiKTa)en
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. Centre for Energy Ethicsen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doihttps://doi.org/10.26434/chemrxiv-2022-20dvn
dc.description.statusPeer revieweden


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