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Effect of Ti-substitution on the properties of P3 structure Na2/3Mn0.8Li0.2O2 showing a ribbon superlattice

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Linnell_2022_Effect_of_Ti_Substitution_on_the_Properties_of_P3_ChemElectroChem_e202200929_CCBY.pdf (1.940Mb)
Date
14/10/2022
Author
Linnell, Stephanie Frances
Kim, Eun Jeong
Ma, Le Anh
Naden, Aaron Benjamin
Irvine, John Thomas Sirr
Younesi, Reza
Duda, Laurent
Armstrong, Robert
Funder
EPSRC
EPSRC
EPSRC
Grant ID
EP/T019298/1
ep/l017008/1
EP/R023751/1
Keywords
Anion redox chemistry
Layered compounds
Positive electrode material
Sodium
Superstructure
QD Chemistry
NDAS
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Abstract
Oxygen anion redox offers an effective strategy to enhance the energy density of layered oxide positive electrodes for sodium- and lithium-ion batteries. However, lattice oxygen loss and irreversible structural transformations over the first cycle may result in large voltage hysteresis, thereby impeding practical application. Herein, ribbon superstructure ordering of Li/transition-metal-ions was applied to suppress the voltage hysteresis combined with Ti-substitution to improve the cycling stability for P3-Na0.67Li0.2Ti0.15Mn0.65O2. When both cation and anion redox reactions are utilized, Na0.67Li0.2Ti0.15Mn0.65O2 delivers a reversible capacity of 172 mA h g−1 after 25 cycles at 10 mA g−1 between 1.6–4.4 V vs. Na+/Na. Ex-situ X-ray diffraction data reveal that the ribbon superstructure is retained with negligible unit cell volume expansion/contraction upon sodiation/desodiation. The performance as a positive electrode for Li-ion batteries was also evaluated and P3-Na0.67Li0.2Ti0.15Mn0.65O2 delivers a reversible capacity of 180 mA h g−1 after 25 cycles at 10 mA g−1 when cycled vs. Li+/Li between 2.0–4.8 V.
Citation
Linnell , S F , Kim , E J , Ma , L A , Naden , A B , Irvine , J T S , Younesi , R , Duda , L & Armstrong , R 2022 , ' Effect of Ti-substitution on the properties of P3 structure Na 2 /3Mn 0.8 Li 0.2 O 2 showing a ribbon superlattice ' , ChemElectroChem , vol. 9 , no. 19 , e202200929 . https://doi.org/10.1002/celc.202200929
Publication
ChemElectroChem
Status
Peer reviewed
DOI
https://doi.org/10.1002/celc.202200929
ISSN
2196-0216
Type
Journal article
Rights
Copyright © 2022 The Authors. ChemElectroChem published by Wiley-VCH GmbH. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
Description
Funding: Faraday Institution (Grant Number(s): FIRG018); Engineering and Physical Sciences Research Council (Grant Number(s): EP/T019298/1, EP/L017008/1, EP/R023751/1); Energimyndigheten (Grant Number(s): 2020-005249); Spring 8 (Grant Number(s): 2019B1604).
Collections
  • University of St Andrews Research
URI
http://hdl.handle.net/10023/26194

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