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Catalytic hydrogenation of urea derivatives and polyureas
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dc.contributor.author | Kumar, Amit | |
dc.contributor.author | Luk, James | |
dc.date.accessioned | 2022-08-25T23:40:08Z | |
dc.date.available | 2022-08-25T23:40:08Z | |
dc.date.issued | 2021-08-26 | |
dc.identifier | 275406954 | |
dc.identifier | 7a90e661-0b5a-45ed-8feb-d23d5726d201 | |
dc.identifier | 85113419788 | |
dc.identifier | 000688748600008 | |
dc.identifier.citation | Kumar , A & Luk , J 2021 , ' Catalytic hydrogenation of urea derivatives and polyureas ' , European Journal of Organic Chemistry , vol. 2021 , no. 32 , pp. 4546-4550 . https://doi.org/10.1002/ejoc.202100775 | en |
dc.identifier.issn | 1434-193X | |
dc.identifier.other | RIS: urn:B931CE5562D8A8A15BA05995A0BEA033 | |
dc.identifier.other | ORCID: /0000-0002-8175-8221/work/99466611 | |
dc.identifier.uri | https://hdl.handle.net/10023/25894 | |
dc.description | AK thanks the Leverhulme Trust for an early career fellowship. JL thanks the University of St. Andrews for the Undergraduate Research Assistantship. | en |
dc.description.abstract | We present here the catalytic hydrogenation of various urea derivatives to amines and methanol. The reaction is catalyzed by a ruthenium or an iridium Macho pincer complex and produces amine and methanol in very good to excellent yields. Moreover, we also expand this concept to demonstrate the first example of the hydrogenative depolymerization of polyureas to produce diamines and methanol in moderate yields. | |
dc.format.extent | 5 | |
dc.format.extent | 1376047 | |
dc.language.iso | eng | |
dc.relation.ispartof | European Journal of Organic Chemistry | en |
dc.subject | Catalysis | en |
dc.subject | Hydrogenation | en |
dc.subject | Pincer | en |
dc.subject | Polyurea | en |
dc.subject | Urea | en |
dc.subject | QD Chemistry | en |
dc.subject | NDAS | en |
dc.subject.lcc | QD | en |
dc.title | Catalytic hydrogenation of urea derivatives and polyureas | en |
dc.type | Journal article | en |
dc.contributor.sponsor | The Leverhulme Trust | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.identifier.doi | https://doi.org/10.1002/ejoc.202100775 | |
dc.description.status | Peer reviewed | en |
dc.date.embargoedUntil | 2022-08-26 | |
dc.identifier.url | https://chemistry-europe.onlinelibrary.wiley.com/doi/toc/10.1002/(ISSN)1099-0690.EaSTCHEM | en |
dc.identifier.grantnumber | ECF-2019-161 | en |
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