Two boron atoms versus one : high-performance deep-blue multi-resonance thermally activated delayed fluorescence emitters
Abstract
Two new deep-blue narrowband multi-resonant emitters, 1B-DTACrs and 2B-DTACrs, one of which shows thermally activated delayed fluorescence (TADF), based on boron, nitrogen, and oxygen doped nanographenes are reported. Devices based on 2B-DTACrs showed an EQEmax of 14.8% and CIE coordinates of (0.150, 0.044), which are very close to the BT.2020 requirement for blue pixels.
Citation
Chan , C-Y , Madayanad Suresh , S , Lee , Y-T , Tsuchiya , Y , Matulaitis , T , Hall , D , Slawin , A M Z , Warriner , S , Beljonne , D , Olivier , Y , Adachi , C & Zysman-Colman , E 2022 , ' Two boron atoms versus one : high-performance deep-blue multi-resonance thermally activated delayed fluorescence emitters ' , Chemical Communications , vol. 58 , no. 67 , pp. 9377-9380 . https://doi.org/10.1039/d2cc03347j
Publication
Chemical Communications
Status
Peer reviewed
ISSN
1359-7345Type
Journal article
Rights
Copyright © 2022 The Author(s). Open Access article. This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.
Description
This work was supported financially by the JSPS Core-to-Core Program (grant number: JPJSCCA20180005) and Kyulux Inc. S. M. S. acknowledges support from the Marie Skłodowska-Curie Individual Fellowship (grant agreement No 838885 NarrowbandSSL). We would like to thank the Leverhulme Trust (RPG-2016-047) for financial support. E. Z.-C. is a Royal Society Leverhulme Trust Senior Research fellow (SRF\R1\201089). We thank the EPRSC for funding (EP/R035164/1). Computational resources have been provided by the Consortium des Équipements de Calcul Intensif (CÉCI), funded by the Fonds de la Recherche Scientifiques de Belgique (F. R. S.-FNRS) under Grant No. 2.5020.11, as well as the Tier-1 supercomputer of the Fédération Wallonie-Bruxelles, infrastructure funded by the Walloon Region under the grant agreement n1117545. Y. O. acknowledges funding by the Fonds de la Recherche Scientifique-FNRS under Grant no. F.4534.21 (MIS-IMAGINE). D. B. is a FNRS Research Director.Collections
Items in the St Andrews Research Repository are protected by copyright, with all rights reserved, unless otherwise indicated.