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New variants of (110)-oriented layered lead bromide perovskites, templated by formamidinium or pyrazolium
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dc.contributor.author | Guo, Yuanyuan | |
dc.contributor.author | Elliott, Clement | |
dc.contributor.author | McNulty, Jason | |
dc.contributor.author | Cordes, David | |
dc.contributor.author | Slawin, Alexandra | |
dc.contributor.author | Lightfoot, Philip | |
dc.date.accessioned | 2022-08-11T23:36:42Z | |
dc.date.available | 2022-08-11T23:36:42Z | |
dc.date.issued | 2021-08-12 | |
dc.identifier | 275131085 | |
dc.identifier | c7315485-3698-49c3-b6ea-efa5ce025783 | |
dc.identifier | 000684112900001 | |
dc.identifier | 85112198094 | |
dc.identifier.citation | Guo , Y , Elliott , C , McNulty , J , Cordes , D , Slawin , A & Lightfoot , P 2021 , ' New variants of (110)-oriented layered lead bromide perovskites, templated by formamidinium or pyrazolium ' , European Journal of Inorganic Chemistry , vol. Early View . https://doi.org/10.1002/ejic.202100433 | en |
dc.identifier.issn | 1434-1948 | |
dc.identifier.other | RIS: urn:9918B43DCF0D924B3AE9F13EFC966A2D | |
dc.identifier.other | ORCID: /0000-0001-7048-3982/work/99115731 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/99115870 | |
dc.identifier.other | ORCID: /0000-0002-5366-9168/work/99115913 | |
dc.identifier.uri | https://hdl.handle.net/10023/25829 | |
dc.description | We acknowledge support from the University of St Andrews, the China Scholarship Council (studentship to YYG) and Leverhulme Trust (RPG-2018-065). | en |
dc.description.abstract | Four new hybrid lead(II) halide perovskites, γ-(FA)2PbBr4, (FA)1.5(AA)0.5PbBr4, (PY)(GA)PbBr4 and (PY)(TZ)PbBr4 ((FA)=formamidinium, (AA)=acetamidinium, (PY)=pyrazolium, (GA)=guanidinium and (TZ)=1,2,3-triazolium), adopt (110)-oriented layered perovskite structures. While (PY) is found to template the formation of ‘conventional’ (110)-oriented structure types (i. e. containing staggered [PbBr4]∞ layers), (FA) is shown to facilitate formation of much less common variants based 3 : 1 ordering of the interlayer species or 3×2 step-like corrugation of the perovskite-like layers themselves. | |
dc.format.extent | 1227382 | |
dc.language.iso | eng | |
dc.relation.ispartof | European Journal of Inorganic Chemistry | en |
dc.subject | Perovskites phases | en |
dc.subject | Hybrid inorganic-organic compounds | en |
dc.subject | Crystal structure | en |
dc.subject | Crystal engineering | en |
dc.subject | Layered compounds | en |
dc.subject | Polymorphism | en |
dc.subject | QD Chemistry | en |
dc.subject | DAS | en |
dc.subject.lcc | QD | en |
dc.title | New variants of (110)-oriented layered lead bromide perovskites, templated by formamidinium or pyrazolium | en |
dc.type | Journal article | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | 10.1002/ejic.202100433 | |
dc.description.status | Peer reviewed | en |
dc.date.embargoedUntil | 2022-08-12 |
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