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Understanding the anion-templated, OSDA-free, interzeolite conversion synthesis of high silica zeolite ZK-5

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dc.contributor.authorLozinska, Magdalena Malgorzata
dc.contributor.authorBruce, Elliott Leigh
dc.contributor.authorMattock, James
dc.contributor.authorChitac, Ruxandra Georgiana
dc.contributor.authorCox, Paul A.
dc.contributor.authorTurrina, Alessandro
dc.contributor.authorWright, Paul Anthony
dc.date.accessioned2022-08-09T10:30:19Z
dc.date.available2022-08-09T10:30:19Z
dc.date.issued2022-10-07
dc.identifier280446009
dc.identifier127722aa-74f6-4288-9db0-268243588aec
dc.identifier85135711183
dc.identifier000837212200001
dc.identifier.citationLozinska , M M , Bruce , E L , Mattock , J , Chitac , R G , Cox , P A , Turrina , A & Wright , P A 2022 , ' Understanding the anion-templated, OSDA-free, interzeolite conversion synthesis of high silica zeolite ZK-5 ' , Chemistry - A European Journal , vol. 28 , no. 56 , e202201689 . https://doi.org/10.1002/chem.202201689en
dc.identifier.issn0947-6539
dc.identifier.otherORCID: /0000-0002-4243-9957/work/117211343
dc.identifier.urihttps://hdl.handle.net/10023/25797
dc.descriptionFunding: Engineering and Physical Sciences Research Council (Grant Number(s): EP/S016201/1, Grant recipient(s): Paul A. Wright, Magdalena M. Lozinska; EP/L017008/1, EP/T019298/1, EP/R023751/1). Engineering and Physical Sciences Research Council (Grant Number(s): EP/S016147/1; Grant recipient(s): James Mattock, Paul A. Cox). Royal Society (Grant Number(s): INF\R2\192052; Grant recipient(s): Paul A. Wright).en
dc.description.abstractHigh silica zeolite ZK-5 (framework Si/Al=4.8) has been prepared by interzeolite conversion from ultrastable zeolite Y via a co-templating route using alkali metal cations and nitrate anions but without organic structure directing agents. The mechanism, which involves zeolite framework – alkali metal cation – nitrate anion ordering, has been established by a combination of chemical and thermal analyses, Raman spectroscopy, computational modelling, and X-ray powder diffraction. Ammonium exchange gives ZK-5 with occluded ammonium nitrate and subsequent heating gives microporous zeolite ZK-5.
dc.format.extent8
dc.format.extent1574740
dc.language.isoeng
dc.relation.ispartofChemistry - A European Journalen
dc.subjectAnion templatingen
dc.subjectInterzeolite conversionen
dc.subjectNitrateen
dc.subjectOSDA-free synthesisen
dc.subjectZeolliteen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleUnderstanding the anion-templated, OSDA-free, interzeolite conversion synthesis of high silica zeolite ZK-5en
dc.typeJournal articleen
dc.contributor.sponsorEPSRCen
dc.contributor.sponsorEPSRCen
dc.contributor.sponsorEPSRCen
dc.contributor.sponsorEPSRCen
dc.contributor.sponsorThe Royal Societyen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. Institute of Behavioural and Neural Sciencesen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doi10.1002/chem.202201689
dc.description.statusPeer revieweden
dc.identifier.grantnumberEP/S016201/1en
dc.identifier.grantnumberep/l017008/1en
dc.identifier.grantnumberEP/T019298/1en
dc.identifier.grantnumberEP/R023751/1en
dc.identifier.grantnumberINF\R2\192052en


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