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The tin sulfates Sn(SO4)2 and Sn2(SO4)3 : crystal structures, optical and thermal properties
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dc.contributor.author | Hämmer, Matthias | |
dc.contributor.author | Netzsch, Philip | |
dc.contributor.author | Klenner, Steffen | |
dc.contributor.author | Neuschulz, Kai | |
dc.contributor.author | Struckmann, Mona | |
dc.contributor.author | Wickleder, Mathias S. | |
dc.contributor.author | Daub, Michael | |
dc.contributor.author | Hillebrecht, Harald | |
dc.contributor.author | Pöttgen, Rainer | |
dc.contributor.author | Höppe, Henning A. | |
dc.date.accessioned | 2022-08-08T23:36:35Z | |
dc.date.available | 2022-08-08T23:36:35Z | |
dc.date.issued | 2021-10-07 | |
dc.identifier | 275629220 | |
dc.identifier | 46c2a74e-d6ce-44a4-8c66-3f440ed15091 | |
dc.identifier | 000686534200001 | |
dc.identifier | 85116524053 | |
dc.identifier.citation | Hämmer , M , Netzsch , P , Klenner , S , Neuschulz , K , Struckmann , M , Wickleder , M S , Daub , M , Hillebrecht , H , Pöttgen , R & Höppe , H A 2021 , ' The tin sulfates Sn(SO 4 ) 2 and Sn 2 (SO 4 ) 3 : crystal structures, optical and thermal properties ' , Dalton Transactions , no. 37 , pp. 12913-12922 . https://doi.org/10.1039/D1DT02189C | en |
dc.identifier.issn | 1477-9226 | |
dc.identifier.other | Bibtex: D1DT02189C | |
dc.identifier.uri | https://hdl.handle.net/10023/25795 | |
dc.description | Funding: H. A. H. and P. N. thank the Deutsche Forschungsgemeinschaft (DFG) for financial support under the project HO 4503/5-1. | en |
dc.description.abstract | We report the crystal structures of two tin(iv) sulfate polymorphs Sn(SO4)2-I (P21/c (no. 14), a = 504.34(3), b = 1065.43(6), c = 1065.47(6) pm, β = 91.991(2)°, 4617 independent reflections, 104 refined parameters, wR2 = 0.096) and Sn(SO4)2-II (P21/n (no. 14), a = 753.90(3), b = 802.39(3), c = 914.47(3) pm, β = 92.496(2)°, 3970 independent reflections, 101 refined parameters, wR2 = 0.033). Moreover, the first heterovalent tin sulfate Sn2(SO4)3 is reported which adopts space group P̄ (no. 2) (a = 483.78(9), b = 809.9(2), c = 1210.7(2) pm, α = 89.007(7)°, β = 86.381(7)°, γ = 73.344(7)°, 1602 independent reflections, 152 refined parameters, wR2 = 0.059). Finally, SnSO4 – the only tin sulfate with known crystal structure – was revised and information complemented. The optical and thermal properties of all tin sulfates are investigated by FTIR, UV-vis, luminescence and 119Sn Mössbauer spectroscopy as well as thermogravimetry and compared. | |
dc.format.extent | 10 | |
dc.format.extent | 3820725 | |
dc.language.iso | eng | |
dc.relation.ispartof | Dalton Transactions | en |
dc.subject | QD Chemistry | en |
dc.subject | DAS | en |
dc.subject | AC | en |
dc.subject | MCC | en |
dc.subject.lcc | QD | en |
dc.title | The tin sulfates Sn(SO4)2 and Sn2(SO4)3 : crystal structures, optical and thermal properties | en |
dc.type | Journal article | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.identifier.doi | 10.1039/D1DT02189C | |
dc.description.status | Peer reviewed | en |
dc.date.embargoedUntil | 2022-08-09 |
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