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Structural diversity in hybrid lead halides templated by 4-methylimidazolium
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dc.contributor.author | Elliott, Clement | |
dc.contributor.author | McNulty, Jason A. | |
dc.contributor.author | Cordes, David B. | |
dc.contributor.author | Slawin, Alexandra M. Z. | |
dc.contributor.author | Lightfoot, Philip | |
dc.date.accessioned | 2022-08-01T23:44:39Z | |
dc.date.available | 2022-08-01T23:44:39Z | |
dc.date.issued | 2021-08-02 | |
dc.identifier | 275200972 | |
dc.identifier | 2fdd6463-3d63-4e6c-8b15-9a1b5c1d5379 | |
dc.identifier | 85112367780 | |
dc.identifier | 000700860100018 | |
dc.identifier.citation | Elliott , C , McNulty , J A , Cordes , D B , Slawin , A M Z & Lightfoot , P 2021 , ' Structural diversity in hybrid lead halides templated by 4-methylimidazolium ' , Journal of Solid State Chemistry , vol. In press , 122466 . https://doi.org/10.1016/j.jssc.2021.122466 | en |
dc.identifier.issn | 0022-4596 | |
dc.identifier.other | ORCID: /0000-0001-7048-3982/work/98196437 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/98196627 | |
dc.identifier.other | ORCID: /0000-0002-5366-9168/work/98196682 | |
dc.identifier.uri | https://hdl.handle.net/10023/25759 | |
dc.description | We acknowledge support from the University of St Andrews and the Leverhulme trust (RPG-2018-065). | en |
dc.description.abstract | We present several new hybrid organic-inorganic lead(II) bromide materials with interesting polyhedral connectivity templated by [4-MeImH] ([4-MeImH] = 4-methylimidazolium). These include two new examples of a 1D structure-type consisting of edge-sharing chains ([4-MeImH]PbBr3 and [4-MeImH]0.6[ImH]0.4PbBr3, [ImH] = imidazolium); the first example of a 2D layered material containing 7-coordinate Pb, and featuring edge- and face-sharing polyhedra ([4-MeImH]Pb2Br5) and two examples of materials consisting of corner- and face-sharing octahedra; [ImH]PbBr3, which has a 4H-perovskite structure and [4-MeImH]4[ImH]5Pb6Br21, which has a structural resemblance to the 4H-perovskite, but incorporates terminal Br ligands leading to a complex layered structure. | |
dc.format.extent | 1523358 | |
dc.language.iso | eng | |
dc.relation.ispartof | Journal of Solid State Chemistry | en |
dc.subject | Single crystal X-ray diffraction | en |
dc.subject | Lead halides | en |
dc.subject | Polyhderal connectivity | en |
dc.subject | Strucutre-directing effects | en |
dc.subject | Hybrid organic-inorganic | en |
dc.subject | QD Chemistry | en |
dc.subject | DAS | en |
dc.subject.lcc | QD | en |
dc.title | Structural diversity in hybrid lead halides templated by 4-methylimidazolium | en |
dc.type | Journal article | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | https://doi.org/10.1016/j.jssc.2021.122466 | |
dc.description.status | Peer reviewed | en |
dc.date.embargoedUntil | 2022-08-02 |
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