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Structural diversity in hybrid lead halides templated by 4-methylimidazolium

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dc.contributor.authorElliott, Clement
dc.contributor.authorMcNulty, Jason A.
dc.contributor.authorCordes, David B.
dc.contributor.authorSlawin, Alexandra M. Z.
dc.contributor.authorLightfoot, Philip
dc.date.accessioned2022-08-01T23:44:39Z
dc.date.available2022-08-01T23:44:39Z
dc.date.issued2021-08-02
dc.identifier.citationElliott , C , McNulty , J A , Cordes , D B , Slawin , A M Z & Lightfoot , P 2021 , ' Structural diversity in hybrid lead halides templated by 4-methylimidazolium ' , Journal of Solid State Chemistry , vol. In press , 122466 . https://doi.org/10.1016/j.jssc.2021.122466en
dc.identifier.issn0022-4596
dc.identifier.otherPURE: 275200972
dc.identifier.otherPURE UUID: 2fdd6463-3d63-4e6c-8b15-9a1b5c1d5379
dc.identifier.otherORCID: /0000-0001-7048-3982/work/98196437
dc.identifier.otherORCID: /0000-0002-9527-6418/work/98196627
dc.identifier.otherORCID: /0000-0002-5366-9168/work/98196682
dc.identifier.otherScopus: 85112367780
dc.identifier.otherWOS: 000700860100018
dc.identifier.urihttps://hdl.handle.net/10023/25759
dc.descriptionWe acknowledge support from the University of St Andrews and the Leverhulme trust (RPG-2018-065).en
dc.description.abstractWe present several new hybrid organic-inorganic lead(II) bromide materials with interesting polyhedral connectivity templated by [4-MeImH] ([4-MeImH] = 4-methylimidazolium). These include two new examples of a 1D structure-type consisting of edge-sharing chains ([4-MeImH]PbBr3 and [4-MeImH]0.6[ImH]0.4PbBr3, [ImH] = imidazolium); the first example of a 2D layered material containing 7-coordinate Pb, and featuring edge- and face-sharing polyhedra ([4-MeImH]Pb2Br5) and two examples of materials consisting of corner- and face-sharing octahedra; [ImH]PbBr3, which has a 4H-perovskite structure and [4-MeImH]4[ImH]5Pb6Br21, which has a structural resemblance to the 4H-perovskite, but incorporates terminal Br ligands leading to a complex layered structure.
dc.language.isoeng
dc.relation.ispartofJournal of Solid State Chemistryen
dc.rightsCopyright © 2021 Elsevier Inc. All rights reserved. This work has been made available online in accordance with publisher policies or with permission. Permission for further reuse of this content should be sought from the publisher or the rights holder. This is the author created accepted manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1016/j.jssc.2021.122466en
dc.subjectSingle crystal X-ray diffractionen
dc.subjectLead halidesen
dc.subjectPolyhderal connectivityen
dc.subjectStrucutre-directing effectsen
dc.subjectHybrid organic-inorganicen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleStructural diversity in hybrid lead halides templated by 4-methylimidazoliumen
dc.typeJournal articleen
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1016/j.jssc.2021.122466
dc.description.statusPeer revieweden
dc.date.embargoedUntil2022-08-02


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