Show simple item record

Files in this item

Thumbnail

Item metadata

dc.contributor.authorPoskin, Thomas J.
dc.contributor.authorPiscelli, Bruno A.
dc.contributor.authorYoshida, Keigo
dc.contributor.authorCordes, David B.
dc.contributor.authorSlawin, Alexandra M. Z.
dc.contributor.authorCormanich, Rodrigo A.
dc.contributor.authorYamada, Shigeyuki
dc.contributor.authorO'Hagan, David
dc.date.accessioned2022-07-07T13:30:23Z
dc.date.available2022-07-07T13:30:23Z
dc.date.issued2022-07-21
dc.identifier280272781
dc.identifier57c31349-615a-4a61-88de-41484ada6150
dc.identifier000816627100001
dc.identifier85133129757
dc.identifier.citationPoskin , T J , Piscelli , B A , Yoshida , K , Cordes , D B , Slawin , A M Z , Cormanich , R A , Yamada , S & O'Hagan , D 2022 , ' Janus faced fluorocyclohexanes for supramolecular assembly : synthesis and solid state structures of equatorial mono-, di- and tri alkylated cyclohexanes and with tri-axial C–F bonds to impart polarity ' , Chemical Communications , vol. 58 , no. 57 , pp. 7968-7971 . https://doi.org/10.1039/D2CC03010Aen
dc.identifier.issn1359-7345
dc.identifier.otherRIS: urn:2D4C1E150F77E3F881F8BE069738BC53
dc.identifier.otherORCID: /0000-0002-0510-5552/work/115309131
dc.identifier.otherORCID: /0000-0002-9527-6418/work/115309289
dc.identifier.otherORCID: /0000-0002-5366-9168/work/115309327
dc.identifier.urihttps://hdl.handle.net/10023/25623
dc.descriptionWe thank the EPSRC for a studentship (TJP) through the CRITICAT Doctoral Training Centre. FAPESP is also gratefully acknowledged for a studentship (BAP, #2021/09716-5) and a Young Researcher Award (RAC, #2018/03910-1).en
dc.description.abstractConcise and general synthesis protocols are reported to generate all-syn mono-, di- and tri-alkylated cyclohexanes where a single fluorine is located on the remaining carbons of the ring. The alkyl groups are positioned to lie equatorially and to have triaxial C–F bonds imparting polarity to these ring systems. Intermolecular electrostatic interactions in the solid-state structure of the trialkylated systems are explored and the resultant supramolecular order opens up prospects for design in soft materials.
dc.format.extent4
dc.format.extent2860436
dc.language.isoeng
dc.relation.ispartofChemical Communicationsen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleJanus faced fluorocyclohexanes for supramolecular assembly : synthesis and solid state structures of equatorial mono-, di- and tri alkylated cyclohexanes and with tri-axial C–F bonds to impart polarityen
dc.typeJournal articleen
dc.contributor.sponsorEPSRCen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.contributor.institutionUniversity of St Andrews. Institute of Behavioural and Neural Sciencesen
dc.contributor.institutionUniversity of St Andrews. Biomedical Sciences Research Complexen
dc.identifier.doihttps://doi.org/10.1039/D2CC03010A
dc.description.statusPeer revieweden
dc.identifier.grantnumberEP/L016419/1en


This item appears in the following Collection(s)

Show simple item record