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Synthesis of palladium complexes derived from amido linked N-heterocyclic carbenes and their use in Suzuki cross coupling reactions
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dc.contributor.author | Chauhan, Rohit Singh | |
dc.contributor.author | Nagar, Suryakant | |
dc.contributor.author | Chatterjee, Sucheta | |
dc.contributor.author | Goswami, Dibakar | |
dc.contributor.author | Cordes, David B. | |
dc.contributor.author | Slawin, Alexandra M. Z. | |
dc.contributor.author | Tawde, Trupti | |
dc.date.accessioned | 2022-06-06T23:47:32Z | |
dc.date.available | 2022-06-06T23:47:32Z | |
dc.date.issued | 2021-07-08 | |
dc.identifier | 274571407 | |
dc.identifier | 1d678c91-8958-427b-b992-a7baab89333b | |
dc.identifier | 000658368400001 | |
dc.identifier | 85107346178 | |
dc.identifier.citation | Chauhan , R S , Nagar , S , Chatterjee , S , Goswami , D , Cordes , D B , Slawin , A M Z & Tawde , T 2021 , ' Synthesis of palladium complexes derived from amido linked N-heterocyclic carbenes and their use in Suzuki cross coupling reactions ' , Zeitschrift für Anorganische und Allgemeine Chemie , vol. Early View , pp. 1334-1341 . https://doi.org/10.1002/zaac.202100150 | en |
dc.identifier.issn | 0044-2313 | |
dc.identifier.other | RIS: urn:0F822F05A973A672BA64642EF15777B1 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/95418397 | |
dc.identifier.other | ORCID: /0000-0002-5366-9168/work/95418419 | |
dc.identifier.uri | https://hdl.handle.net/10023/25494 | |
dc.description | One of the authors (RSC) is grateful to DST for the financial support under the DST young scientist scheme YSS/2014/000797. | en |
dc.description.abstract | Treatment of 1-(n-butyl)-3-N-(2-Ar)acetamido-1, 3-imidazolium chloride (Ar=furylmethyl,phenylmethyl) with excess K2CO3 and [PdCl2(L−L)] (L−L=2 PPh3, dppf) afforded orange compounds of composition [(1-(n-butyl)-3-N-(2-Ar)acetamido-1,3-imidazol-2-ylidene)]2Pd (Ar=furylmethyl; phenylmethyl). These complexes were characterized by NMR (1H and 13C{1H} NMR), IR and micro-analysis data. Subsequently, the catalytic efficiency of these complexes for cross coupling reactions between 4-haloarenens (halo=Br, I) and phenylboronic acid was studied under different solvents (acetonitrile, THF and DMF), temperatures with different catalyst loadings. The molecular structure of [(1-(n-butyl)-3-N-(2-furylmethyl)acetamido-1, 3-imidazol-2-ylidene)]2Pd was established by single crystal X-ray diffraction analysis. | |
dc.format.extent | 9 | |
dc.format.extent | 581135 | |
dc.language.iso | eng | |
dc.relation.ispartof | Zeitschrift für Anorganische und Allgemeine Chemie | en |
dc.subject | N-heterocyclic carbene | en |
dc.subject | [PdCl2(P−P)] | en |
dc.subject | NMR | en |
dc.subject | Suzuki Cross coupling | en |
dc.subject | QD Chemistry | en |
dc.subject | DAS | en |
dc.subject | AC | en |
dc.subject.lcc | QD | en |
dc.title | Synthesis of palladium complexes derived from amido linked N-heterocyclic carbenes and their use in Suzuki cross coupling reactions | en |
dc.type | Journal article | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | https://doi.org/10.1002/zaac.202100150 | |
dc.description.status | Peer reviewed | en |
dc.date.embargoedUntil | 2022-06-07 |
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